35750-24-4

Basic information

• Product Name: methyl 4-(prop-2-en-1-yloxy)benzoate
• Synonyms: RARECHEM AL BF 0237;Methyl 4-(allyloxy)benzoate;Methyl 4-(prop-2-en-1-yloxy)benzoate
• CAS NO: 35750-24-4
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.2112
• Mol File: 35750-24-4.mol
• Article Data: 41

Chemical Properties

• Boiling Point: 289.6°C at 760 mmHg
• Flash Point: 117°C
• Density: 1.071g/cm³
• Vapor Pressure: 0.00218mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: methyl 4-(prop-2-en-1-yloxy)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-(prop-2-en-1-yloxy)benzoate(35750-24-4)
• EPA Substance Registry System: methyl 4-(prop-2-en-1-yloxy)benzoate(35750-24-4)

Safety Data

• Hazardous Substances Data: 35750-24-4(Hazardous Substances Data)

Upstream product

• 556-56-9 allyl iodid 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 106-95-6 allyl bromide 
• 67-56-1 methanol 
• 27914-60-9 4-allyloxybenzoic acid 
• 99-96-7 4-hydroxy-benzoic acid 
• 106-93-4 ethylene dibromide 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 107-18-6 allyl alcohol 
• 107-05-1 3-chloroprop-1-ene 
• 40663-68-1 4-(2-propenyloxy)benzaldehyde 

Downstream Products

• 99-76-3 methyl 4-hydroxylbenzoate 
• 124172-25-4 cis-4-<<3-(4-chlorophenyl)-2-methyl-3-<(1H-1,2,4-triazol-1-yl)methyl>isoxazolidin-5-yl>methoxy>benzoic acid 
• 383985-85-1 C₁₁H₁₃Cl₃O₃Si 
• 1142229-39-7 methyl 4-(2-cyclopentylideneethoxy)benzoate 
• 83953-73-5 cholesteryl 4-(2-propenyloxy)benzoate 
• 153275-21-9 [4-(2-Ethyl-5,7-dimethyl-imidazo[4,5-b]pyridin-3-ylmethyl)-2,6-dipropyl-phenoxy]-m-tolyl-acetic acid ethyl ester 

Relevant articles and documents

Elastase Inhibitor Cyclotheonellazole A: Total Synthesis and in Vivo Biological Evaluation for Acute Lung Injury

Acute lung injury/acute respiratory distress syndrome (ALI/ARDS) is one of the most common complications in COVID-19. Elastase has been recognized as an important target to prevent ALI/ARDS in the patient of COVID-19. Cyclotheonellazole A (CTL-A) is a nat

Electro-Oxidative Selective Esterification of Methylarenes and Benzaldehydes

A mild and green electro-oxidative protocol to construct aromatic esters from methylarenes and alcohols is herein reported. Importantly, the reaction is free of metals, chemical oxidants, bases, acids, and operates at room temperature. Moreover, the design of the electrolyte was found critical for the oxidation state and structure of the coupling products, a rarely documented effect. This electro-oxidative coupling process also displays exceptional tolerance of many fragile easily oxidized functional groups such as hydroxy, aldehyde, olefin, alkyne, as well as neighboring benzylic positions. The enantiomeric enrichment of some chiral alcohols is moreover preserved during this electro-oxidative coupling reaction, making it overall a promising synthetic tool.

Nickel-catalyzed removal of alkene protecting group of phenols, alcohols via chain walking process

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alcoholic ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group.