3590-07-6

Basic information

• Product Name: Triethylamine, 2,2'-dichloro-, hydrochloride
• Synonyms: Ethylbis(beta-chloroethyl)amine hydrochloride;Hn1 .HCl;Hn1 hydrochloride;N,N-Bis(2-chloroethyl)ethylamine hydrochloride;Tl 329 hydrochloride;Triethylamine, 2,2'-dichloro-, hydrochloride;2-Chloro-N-(2-chloroethyl)-N-ethylethanaMine hydrochloride;EthanaMine, 2-chloro-N-(2-chloroethyl)-N-ethyl-, hydrochloride
• CAS NO: 3590-07-6
• Molecular Formula: C₆H₁₃Cl₂N*ClH
• Molecular Weight: 206.543
• Mol File: 3590-07-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 135.7°Cat760mmHg
• Flash Point: 35.9°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 7.63mmHg at 25°C
• CAS DataBase Reference: Triethylamine, 2,2'-dichloro-, hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: Triethylamine, 2,2'-dichloro-, hydrochloride(3590-07-6)
• EPA Substance Registry System: Triethylamine, 2,2'-dichloro-, hydrochloride(3590-07-6)

Safety Data

• Hazardous Substances Data: 3590-07-6(Hazardous Substances Data)

Usage

General Description

Triethylamine, 2,2'-dichloro-, hydrochloride is a chemical compound that is a hydrochloride salt of triethylamine and 2,2'-dichloroethylamine. It is commonly used as a catalyst or reagent in organic synthesis, and as a corrosion inhibitor in the petroleum industry. Triethylamine, 2,2'-dichloro-, hydrochloride is also utilized in the production of pharmaceuticals and agrochemicals, and as a solvent in chemical reactions. It is important to handle this chemical with caution, as it can be harmful if ingested, inhaled, or comes into contact with the skin or eyes. Additionally, it may have adverse environmental effects and should be used and disposed of properly to minimize its impact.

InChI:InChI=1/C6H13Cl2N.ClH/c1-2-9(5-3-7)6-4-8;/h2-6H2,1H3;1H

Upstream product

• 139-87-7 ethyldiethanolamine 

Downstream Products

• 4669-20-9 ethylcholine mustard 
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• 239797-41-2 1-ethyl-4-(4-butoxybenzenesulfonyl)piperidine-4-carboxylic acid 
• 212770-89-3 1-ethyl-4-(4-methoxy-benzenesulfonyl)-piperidine-4-carboxylic acid 
• 110-89-4 piperidine 
• 239797-44-5 4-[4-(4-chlorophenoxy)benzenesulfonyl]-1-ethylpiperidine-4-carboxylic acid ethyl ester 
• 239797-40-1 1-ethyl-4-(4-butoxybenzenesulfonyl)piperidine-4-carboxylic acid ethyl ester 
• 212770-88-2 1-ethyl-4-(4-methoxy-benzenesulfonyl)-piperidine-4-carboxylic acid ethyl ester 
• 106896-76-8 1-Ethyl-4-(3-methoxy-phenyl)-piperidine-4-carbonitrile 

Relevant articles and documents

Mass spectral studies of silyl derivatives of partially hydrolyzed products of nitrogen mustards: Important markers of nitrogen mustard exposure

Rationale: Nitrogen mustards (NMs) are vesicant class of chemical warfare agents. From the viewpoint of the Chemical Weapons Convention partially hydrolyzed products of nitrogen mustards (pHpNMs) are considered as important markers of nitrogen mustard exposure. The detection of pHpNMs from biological or environmental samples is highly useful for obtaining forensic evidence of exposure to NMs. Methods: Gas chromatography interfaced with tandem mass spectrometry (GC/MS/MS) is a widely used tool for the identification and sensitive detection of metabolites of NMs in complex matrices. The pHpNMs were derivatized using silylating agents as they are highly polar and non-amenable to GC. The mass spectral studies of these silyl derivatives of pHpNMs were performed using GC/MS/MS in both electron ionization (EI) and chemical ionization (CI) mode. Results: Various approaches have been proposed to assess the fragmentation pathways of the trimethylsilyl (TMS) and tert-butyldimethylsilyl (TBDMS) derivatives of pHpNMs. All the proposed fragmentation pathways were based on the product and/or precursor ion scanning of corresponding ions in both EI and CI mode. In the case of EI, most of the fragmentation pathways involved either α-cleavage or inductive cleavage. Conclusions: This is the first report on the MS study of the silyl derivatives of pHpNMs. The study of the two different derivatives of pHpNMs using both EI- and CI-MS provides a reliable, unambiguous identification of pHpNMs in complex environmental and biomedical matrices (such as plasma and urine) during any verification activities.

Crown Ether Annelated Tetrathiafulvalenes. 2

A synthetic procedure leading to derivatives of tetrathiafulvalene (TTF) incorporating polyether chains of various lengths, some nitrogen analogs, and a 2,6-bis(methylene)pyridine analog has been developed.These compounds possess cage-type structures which were confirmed by X-ray crystallography in four cases, two of which are reported herein for the first time.Structural and electronic features of these cage molecules were correlated to oxidation potentials by the use of semiempirical methods (MNDO-PM3).An investigation of the alkali metal ion affinity using PDMS revealed that these compounds are poor ligands.Finally, in one case, protonation of the core TTF was studied by NMR.