360574-95-4Relevant articles and documents
One-pot synthesis of nitronaphthalenes from Morita-Baylis-Hillman acetates and primary nitroalkanes via sequential SN2′-intramolecular oxidative nucleophilic substitution of hydrogen-E2 elimination
Kim, Su Yeon,Kim, Ko Hoon,Min, Beom Kyu,Kim, Jimin,Kim, Jae Nyoung
, p. 946 - 949 (2016)
-
Copper and copper-manganese 1D coordination polymers: Synthesis optimization, crystal structure and preliminary studies as catalysts for Baylis–Hillman reactions
Alves Júnior, Severino,Chojnacki, Jaroslaw,Lima-Junior, Claudio Gabriel,Silva, Lucas Araujo Trajano,Vasconcellos, Mário Luiz Araújo de Almeida,da Silva, Fausthon Fred,da Silva, R. B.,de Andrade, Julyanna Candido Dutra
, (2021)
This work reports the influence of experimental parameters (pH and counter-ion) in the synthesis of the 1D coordination polymer [Cu(IDA)(H2O)2]n (IDA = iminodiacetate), named here Cu-IDA. Copper-manganese bimetallic coordi
Phosphine-Catalyzed [3 + 2] Annulation of Morita-Baylis-Hillman Carbonates with Isoxazole-Based Alkenes
Liao, Jianning,Dong, Jipan,Xu, Jiaqing,Wang, Wei,Wu, Yongjun,Hou, Yuxia,Guo, Hongchao
supporting information, p. 2090 - 2099 (2021/02/05)
A phosphine-catalyzed [3 + 2] annulation of Morita-Baylis-Hillman (MBH) carbonates with 3-methyl-4-nitro-5-styrylisoxazoles has been developed to afford various multifunctional isoxazoles in moderate to good yields with moderate to excellent diastereoselectivities. With a spirocyclic chiral phosphine as the catalyst, up to 89% ee was obtained.
Enantioselective Lewis base catalyzed phosphonyldifluoromethylation of allylic fluorides using a: C -silyl latent pronucleophile
Zi, You,Lange, Markus,Vilotijevic, Ivan
supporting information, p. 5689 - 5692 (2020/06/19)
The first enantioselective phosphonyldifluoromethylation is enabled by the use of diethyl (difluoro(trimethylsilyl)-methyl)phosphonate reagent as a latent pronucleophile in the Lewis base catalyzed substitution of allylic fluorides. The reaction proceeds
