3617-44-5

Basic information

• Product Name: L-PHENYLALANINE
• Synonyms: Phenyalanine, L-; Phenylalanine; PHE; Phenylalanine, L-; (S)-2-Amino-3-Phenylpropionic acid; (S)-(-)-Phenylalanine; H-L-PHE-OH; (S)-2-Amino-3-phenylpropionic acid~H-Phe-OH; L-beta-Phenylalanine; H-Phe-OH; L(-)Phenylalaniline; L-Phenylalanie
• CAS NO: 3617-44-5
• Molecular Formula: C₉H₁₁NO₂
• Molecular Weight: 0
• EINECS: 200-568-1
• Mol File: 3617-44-5.mol
• Article Data: 1

Chemical Properties

• Melting Point: 270-275℃
• Boiling Point: 329.5°C at 760 mmHg
• Flash Point: 153.1°C
• Appearance: /
• Density: 1.164g/cm³
• Vapor Pressure: 7.09E-05mmHg at 25°C
• Refractive Index: 1.564
• Water Solubility: 1-5 g/100 mL at 25℃
• CAS DataBase Reference: L-PHENYLALANINE(CAS DataBase Reference)
• NIST Chemistry Reference: L-PHENYLALANINE(3617-44-5)
• EPA Substance Registry System: L-PHENYLALANINE(3617-44-5)

Safety Data

• Statements: R36/37/38:
• Safety Statements: S24/25:; S37/39:
• Hazardous Substances Data: 3617-44-5(Hazardous Substances Data)

Usage

InChI:InChI:1S/C9H11NO2/c10-8(9(11)12)6-7-4-2-1-3-5-7/h1-5,8H,6,10H2,(H,11,12)

Upstream product

• 40940-57-6 (S)-(N-Allyloxycarbonyl)phenylalanine 

Relevant articles and documents

PALLADIUM-CATALYZED REACTION OF ALLYL CARBAMATES; ALLYLATION OF CARBONUCLEOPHILES, AND PROTECTION-DEPROTECTION OF AMINES

Allylation of carbonucleophiles with allylic carbamates under neutral conditions has been studied.The C-allylation of carbonucleophile is competitive with the N-allylation of amines, and the structure of amines is crucial for the selectivity.Bulky secondary amines gave the best results.Also a new method of protection-deprotection of amines as carbamates has been developed.Smooth deprotection is possible by the palladium-catalyzed reaction of allyl carbamates with formic acid.This method is particulary useful for primary amines, including optically active amino acids.