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3710-84-7

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3710-84-7 Usage

Description

N,N-Diethylhydroxylamine is a colorless and transparent liquid with a boiling point of 125-130 °C and an ammonia odor. It is easily soluble in water, soluble in ethanol, ether, chloroform and benzene.

Chemical Properties

liquid

Uses

Different sources of media describe the Uses of 3710-84-7 differently. You can refer to the following data:
1. N,N-Diethylhydroxylamine has the following various uses:1.As a vinyl monomer, used in efficient inhibitor agent of conjugate olefins. 2.In liquid or gas phase, if end gather seed is existed,it can be used as inhibitors of end gather. 3.It's a excellent end agent in process of Emulsion-polymerized styrene butadiene rubber. 4.It's a antioxidants of the unsaturated oil and resin. 5.In the environmental protection,it’s good photochemical smoke inhibitors. 6.It's used as corrosion inhibitors in the equipment of the boiler feed water and steam heat exchange. 7.It's used as antioxidant in photography screens potions.
2. Diethylhydroxylamine has been suggested as a stabilizer for color forma-tion for monoalkylphenols and phenolic antioxidants. It has also been reported to stabilize emulsions used in the latex industry and for Spandex rubber, as well as a reducing agent for quinones and a monomer stabilizer or inhibitor.
3. N,N-Diethylhydroxylamine may be employed as a ligand in the preparation of unsymmetric mixed ligand oxadiazoline and/or imine platinum complexes. It may be used in the synthesis of organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc.

General Description

The product is 85wt.% solution of N,N-diethylhydroxylamine. The reaction of N,N-diethylhydroxylamine with tert-butylhydroperoxide has been studied. It participates in the preparation of symmetrical and an isomeric mixture of unsymmetrical phthalocyanines. It undergoes degradation on exposure to radiation and affords light hydrocarbons. Qualitative and quantitative analyses of the produced hydrocarbons have been reported. It also participates in the conversion of quinones and quinonemonosulfonimide to the corresponding hydroquinones and sulfonylaminophenols, respectively.

Health effects

The effects of diethylhydroxylamine (DEHA), a potent free-radical scavenger, on lipid peroxidation of rat liver microsomes were investigated in vitro. DEHA strongly inhibited ascorbate-dependent nonenzymatic microsomal lipid peroxidation. It also completely inhibited nonenzymatic lipid peroxidation of heat-denatured microsomes, indicating that inhibition is protein-independent. DEHA only moderately inhibited NADPH-dependent enzymatic microsomal lipid peroxidation.

Safety Profile

Poison by skin contact. Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Check Digit Verification of cas no

The CAS Registry Mumber 3710-84-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,7,1 and 0 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 3710-84:
(6*3)+(5*7)+(4*1)+(3*0)+(2*8)+(1*4)=77
77 % 10 = 7
So 3710-84-7 is a valid CAS Registry Number.
InChI:InChI=1/C4H11NO.C2H2O4/c1-3-5(6)4-2;3-1(4)2(5)6/h6H,3-4H2,1-2H3;(H,3,4)(H,5,6)

3710-84-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (B23302)  N,N-Diethylhydroxylamine, 97%   

  • 3710-84-7

  • 25g

  • 219.0CNY

  • Detail
  • Alfa Aesar

  • (B23302)  N,N-Diethylhydroxylamine, 97%   

  • 3710-84-7

  • 100g

  • 631.0CNY

  • Detail
  • Aldrich

  • (471593)  N,N-Diethylhydroxylamine  ≥98%

  • 3710-84-7

  • 471593-100ML

  • 338.13CNY

  • Detail
  • Aldrich

  • (471593)  N,N-Diethylhydroxylamine  ≥98%

  • 3710-84-7

  • 471593-500ML

  • 1,175.85CNY

  • Detail
  • Aldrich

  • (471593)  N,N-Diethylhydroxylamine  ≥98%

  • 3710-84-7

  • 471593-2L

  • 3,576.69CNY

  • Detail
  • Aldrich

  • (473235)  N,N-Diethylhydroxylaminesolution  85 wt. % in H2O

  • 3710-84-7

  • 473235-250G

  • 358.02CNY

  • Detail
  • Aldrich

  • (473235)  N,N-Diethylhydroxylaminesolution  85 wt. % in H2O

  • 3710-84-7

  • 473235-2KG

  • 1,876.68CNY

  • Detail

3710-84-7Synthetic route

diethylamine
109-89-7

diethylamine

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With 2-hydroxy-N,N,N-trimethyl ethanaminium peroxydisulfate at 20℃; for 1h; Inert atmosphere; Green chemistry; chemoselective reaction;94%
31%
With dihydrogen peroxide
With dihydrogen peroxide
With dihydrogen peroxide
acetaldehyde
75-07-0

acetaldehyde

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
palladium-carbon In methanol54%
C16H20NO2P
102269-06-7

C16H20NO2P

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With sulfuric acid In methanol for 2h; Heating;41%
ethylmagnesium iodide
10467-10-4

ethylmagnesium iodide

Nitroethane
79-24-3

Nitroethane

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether und Zers. des Reaktionsproduktes mit Wasser;
ethylmagnesium iodide
10467-10-4

ethylmagnesium iodide

Nitroethane
79-24-3

Nitroethane

A

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

B

N-ethyl-N-sec-butyl-hydroxylamine
65616-18-4

N-ethyl-N-sec-butyl-hydroxylamine

Conditions
ConditionsYield
With diethyl ether und Zers. des Reaktionsproduktes mit Wasser;
ethylmagnesium iodide
10467-10-4

ethylmagnesium iodide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether; Nitrogen dioxide und Zerlegen des oeligen Prod. mit Wasser;
Nitroethane
79-24-3

Nitroethane

ethyl magnesium (1+); iodide

ethyl magnesium (1+); iodide

A

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

B

N-ethyl-N-sec-butyl-hydroxylamine
65616-18-4

N-ethyl-N-sec-butyl-hydroxylamine

diethyl ether
60-29-7

diethyl ether

ethyl nitrate
625-58-1

ethyl nitrate

ethylmagnesium bromide

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethyl ether
60-29-7

diethyl ether

1,2-ethyl dinitrate
628-96-6

1,2-ethyl dinitrate

ethylmagnesium bromide

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethyl ether
60-29-7

diethyl ether

Pentaerythritol tetranitrate
78-11-5

Pentaerythritol tetranitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
und Zersetzung des Reaktionsprodukts mit Wasser;
diethyl ether
60-29-7

diethyl ether

Pentaerythritol tetranitrate
78-11-5

Pentaerythritol tetranitrate

ethylmagnesium bromide

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethyl ether
60-29-7

diethyl ether

glycerin trinitrate
55-63-0

glycerin trinitrate

ethylmagnesium bromide

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

ethyl nitrate
625-58-1

ethyl nitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether
ethyl nitrate
625-58-1

ethyl nitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

A

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

B

diethylamine
109-89-7

diethylamine

Conditions
ConditionsYield
With diethyl ether Zersetzen des Reaktionsprodukts mit Wasser;
1,2-ethyl dinitrate
628-96-6

1,2-ethyl dinitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether
Pentaerythritol tetranitrate
78-11-5

Pentaerythritol tetranitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether
triethylamine N-oxide
2687-45-8

triethylamine N-oxide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

glycerin trinitrate
55-63-0

glycerin trinitrate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether
diethyl-benzyl-amine oxide
854182-24-4

diethyl-benzyl-amine oxide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
at 100 - 180℃; under 1 Torr;
diethyl-benzyl-amine oxide
854182-24-4

diethyl-benzyl-amine oxide

A

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

B

N-ethyl-N,O-dibenzyl-hydroxylamine

N-ethyl-N,O-dibenzyl-hydroxylamine

C

N-benzyl-N-ethylhydroxylamine
65616-26-4

N-benzyl-N-ethylhydroxylamine

D

N,N-diethyl-O-benzyl-hydroxylamine
27694-73-1

N,N-diethyl-O-benzyl-hydroxylamine

Conditions
ConditionsYield
at 180℃; under 1 Torr; in einer Stickstoff-Atmosphaere; Prod.5: Aethylen;
diethylzinc
557-20-0

diethylzinc

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether; nitrosylchloride nach einigen Stunden zersetzt man mit Wasser;
ethyl iodide
75-03-6

ethyl iodide

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With hydroxylamine
chloroform
67-66-3

chloroform

acetyl cyclohexanesulfonyl peroxide
3179-56-4

acetyl cyclohexanesulfonyl peroxide

diethylamine
109-89-7

diethylamine

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethylzinc
557-20-0

diethylzinc

N-nitrosodiphenylamine
382165-80-2

N-nitrosodiphenylamine

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

ethylzinc iodide
999-75-7

ethylzinc iodide

isopentyl nitrite
110-46-3

isopentyl nitrite

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether und Zers. des Reaktionsproduktes mit Wasser;
ethylmagnesium iodide
10467-10-4

ethylmagnesium iodide

isopentyl nitrite
110-46-3

isopentyl nitrite

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether und Zers. des Reaktionsproduktes mit Wasser;
diethylzinc
557-20-0

diethylzinc

isopentyl nitrite
110-46-3

isopentyl nitrite

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Conditions
ConditionsYield
With diethyl ether das Produkt wird nach mehreren Monaten mit Wasser zersetzt;
ethyl magnesium (1+); iodide

ethyl magnesium (1+); iodide

isopentyl nitrite
110-46-3

isopentyl nitrite

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

ethyl zinc iodide

ethyl zinc iodide

isopentyl nitrite
110-46-3

isopentyl nitrite

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethylamine
109-89-7

diethylamine

A

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

B

3-aza-2-pentene
1190-79-0

3-aza-2-pentene

C

N,N'-diethyl-2,3-butanediamine
3653-18-7

N,N'-diethyl-2,3-butanediamine

Conditions
ConditionsYield
With oxygen Quantum yield; Ambient temperature; Irradiation; Hg-sensitized photolysis presence and absence O2, or N2O at various pressure and time;
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

N-ethyl-N-ethylideneamine N-oxide
70524-55-9, 81206-52-2, 81206-53-3

N-ethyl-N-ethylideneamine N-oxide

Conditions
ConditionsYield
With ~ 5 mol% gold on silica In methanol at 20℃; for 16h; chemoselective reaction;100%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dichloromethane at 20℃; for 2h; Mechanism; Reagent/catalyst; Solvent;96%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dichloromethane at 20℃; for 2h;96%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

2,4,6-trichlorobenzoyl chloride
4136-95-2

2,4,6-trichlorobenzoyl chloride

N,N-diethyl-O-(2,4,6-trichlorobenzoyl)hydroxylamine

N,N-diethyl-O-(2,4,6-trichlorobenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.333333h;100%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

1-(((5-chloro-3,3-difluoropent-4-yn-1-yl)oxy)methyl)-4-methoxybenzene

1-(((5-chloro-3,3-difluoropent-4-yn-1-yl)oxy)methyl)-4-methoxybenzene

(Z)-1-chloro-N,N-diethyl-3,3-difluoro-5-((4-methoxybenzyl)oxy)pent-1-en-1-amine N-oxide

(Z)-1-chloro-N,N-diethyl-3,3-difluoro-5-((4-methoxybenzyl)oxy)pent-1-en-1-amine N-oxide

Conditions
ConditionsYield
In chloroform; 2,2,2-trifluoroethanol at 22.5℃; for 3h; Kinetics; Inert atmosphere;100%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

1-((2-((1,1-difluoroprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

1-((2-((1,1-difluoroprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

(E)-N,N-diethyl-3,3-difluoro-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

(E)-N,N-diethyl-3,3-difluoro-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

Conditions
ConditionsYield
In chloroform; 2,2,2-trifluoroethanol at 60℃; for 0.666667h; Kinetics; Inert atmosphere;100%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

N,N-diethyl-O-(4-methoxybenzoyl)hydroxylamine

N,N-diethyl-O-(4-methoxybenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.75h;99%
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;94%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

mesitylene-2-carboxylic acid chloride
938-18-1

mesitylene-2-carboxylic acid chloride

N,N-diethyl-O-(2,4,6-trimethylbenzoyl)hydroxylamine
936138-68-0

N,N-diethyl-O-(2,4,6-trimethylbenzoyl)hydroxylamine

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2.5h;99%
With dmap; triethylamine In dichloromethane at 20℃; for 0.5h;63%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

N,N-diethylhydroxylamine potassium salt
90527-23-4

N,N-diethylhydroxylamine potassium salt

Conditions
ConditionsYield
With potassium hydride In pentane at -78 - 20℃; Inert atmosphere;99%
cyclooctyne
1781-78-8

cyclooctyne

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

(E)-N,N-diethylcyclooct-1-en-1-amine oxide

(E)-N,N-diethylcyclooct-1-en-1-amine oxide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.166667h; Kinetics; Solvent; Inert atmosphere;99%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

1-((2-((1,1-difluoro-3-iodoprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

1-((2-((1,1-difluoro-3-iodoprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

(Z)-N,N-diethyl-3,3-difluoro-1-iodo-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

(Z)-N,N-diethyl-3,3-difluoro-1-iodo-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

Conditions
ConditionsYield
In chloroform; 2,2,2-trifluoroethanol at 60℃; for 0.5h; Kinetics; Inert atmosphere;99%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

benzoyl chloride
98-88-4

benzoyl chloride

N,N-diethyl-O-benzoylhydroxylamine
61582-64-7

N,N-diethyl-O-benzoylhydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.5h;98%
With triethylamine In dichloromethane at 20℃; for 0.666667h;98%
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere;98%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

ortho-toluoyl chloride
933-88-0

ortho-toluoyl chloride

N,N-diethyl-O-(2-methylbenzoyl)hydroxylamine

N,N-diethyl-O-(2-methylbenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;96%
With dmap; triethylamine In dichloromethane at 20℃; for 3h;89%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

trans-[PtCl4(NH=(Me)C-ONEt2)2]
245414-26-0

trans-[PtCl4(NH=(Me)C-ONEt2)2]

Conditions
ConditionsYield
In acetonitrile 20-25°C, 1 d; solvent removal (vac.), washing (Et2O); elem. anal.;96%
2-Thiophenecarbonyl chloride
5271-67-0

2-Thiophenecarbonyl chloride

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

N,N-diethyl-O-(thiophene-2-carbonyl)hydroxylamine
1621478-71-4

N,N-diethyl-O-(thiophene-2-carbonyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;96%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

naphthalene-1-carbonic acid chloride
879-18-5

naphthalene-1-carbonic acid chloride

N,N-diethyl-O-(1-naphthoyl)hydroxylamine
1621478-72-5

N,N-diethyl-O-(1-naphthoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;96%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

N,N-diethyl-O-(4-chlorobenzoyl)hydroxylamine
1621478-66-7

N,N-diethyl-O-(4-chlorobenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;95%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

3-Methylbenzoyl chloride
1711-06-4

3-Methylbenzoyl chloride

N,N-diethyl-O-(3-methylbenzoyl)hydroxylamine
1621478-69-0

N,N-diethyl-O-(3-methylbenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;95%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Methacryloyl chloride
920-46-7

Methacryloyl chloride

N,N-diethyl-O-methacryloylhydroxylamine
44979-02-4

N,N-diethyl-O-methacryloylhydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;95%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

2,6-Dichlorobenzoyl chloride
4659-45-4

2,6-Dichlorobenzoyl chloride

O-(2,6-dichlorobenzoyl)-N,N-diethylhydroxylamine

O-(2,6-dichlorobenzoyl)-N,N-diethylhydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;95%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

(1R,8S,9S)‐bicyclo[6.1.0]non‐4‐yn‐9‐ylmethanol
1263166-90-0

(1R,8S,9S)‐bicyclo[6.1.0]non‐4‐yn‐9‐ylmethanol

(1R,8S,9S,E)-N,N-diethyl-9-(hydroxymethyl)bicyclo[6.1.0]non-4-en-4-amine oxide

(1R,8S,9S,E)-N,N-diethyl-9-(hydroxymethyl)bicyclo[6.1.0]non-4-en-4-amine oxide

Conditions
ConditionsYield
In methanol; acetonitrile at 20℃; for 0.166667h; Kinetics; Solvent; Inert atmosphere;95%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

1-((2-((3-bromo-1,1-difluoroprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

1-((2-((3-bromo-1,1-difluoroprop-2-yn-1-yl)oxy)ethoxy)methyl)-4-methoxybenzene

(Z)-1-bromo-N,N-diethyl-3,3-difluoro-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

(Z)-1-bromo-N,N-diethyl-3,3-difluoro-3-(2-((4-methoxybenzyl)oxy)ethoxy)prop-1-en-1-amine N-oxide

Conditions
ConditionsYield
In chloroform; 2,2,2-trifluoroethanol at 60℃; for 0.25h; Kinetics; Inert atmosphere;95%
Cp*TiCl3
12129-06-5

Cp*TiCl3

N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

Cp*Ti(Cl)2(ONEt2)
1097730-83-0

Cp*Ti(Cl)2(ONEt2)

Conditions
ConditionsYield
With N-butyl lithium In hexane; toluene under N2 atm. n-BuLi in hexane was added dropwise to soln. HONEt2 in toluene at 0°C and stirred for 30 min, suspn. Ti complex in toluene was added at -78°C, stirred for 4 h at room temp.; soln. was filtered and evapd. in vacuo; elem. anal.;94.7%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

cyclooct-2-yn-1-yl (4-nitrophenyl)carbamate

cyclooct-2-yn-1-yl (4-nitrophenyl)carbamate

(E)-N,N-diethyl-3-(((4-nitrophenyl)carbamoyl)oxy)cyclooct-1-en-1-amine oxide

(E)-N,N-diethyl-3-(((4-nitrophenyl)carbamoyl)oxy)cyclooct-1-en-1-amine oxide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.166667h; Kinetics; Solvent; Inert atmosphere;94%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

3,3-difluorocyclooct-1-yne

3,3-difluorocyclooct-1-yne

(E)-N,N-diethyl-3,3-difluorocyclooct-1-en-1-amine oxide

(E)-N,N-diethyl-3,3-difluorocyclooct-1-en-1-amine oxide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.0833333h; Kinetics; Solvent; Inert atmosphere;94%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

N,N-diethyl-O-(4-methylbenzoyl)hydroxylamine
1621478-65-6

N,N-diethyl-O-(4-methylbenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;92%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

4-fluorobenzoyl chloride
403-43-0

4-fluorobenzoyl chloride

N,N-diethyl-O-(4-fluorobenzoyl)hydroxylamine
1621478-67-8

N,N-diethyl-O-(4-fluorobenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;92%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

4-trifluoromethyl-phenyl acetyl chloride
329-15-7

4-trifluoromethyl-phenyl acetyl chloride

N,N-diethyl-O-(4-(trifluoromethyl)benzoyl)hydroxylamine
1621478-68-9

N,N-diethyl-O-(4-(trifluoromethyl)benzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;92%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

3,5-dichlorobenzoyl chloride
2905-62-6

3,5-dichlorobenzoyl chloride

N,N-diethyl-O-(3,5-dichlorobenzoyl)hydroxylamine
1621478-70-3

N,N-diethyl-O-(3,5-dichlorobenzoyl)hydroxylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.666667h; Inert atmosphere; Schlenk technique;92%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

diethylzinc
557-20-0

diethylzinc

Zn(OZn(C2H5)N(C2H5)2)4(ON(C2H5)2)2
948296-99-9

Zn(OZn(C2H5)N(C2H5)2)4(ON(C2H5)2)2

Conditions
ConditionsYield
In tetrahydrofuran; hexane byproducts: C2H6; N2, a soln. of N compd. (THF) slowly added to a soln. of Zn compd. (hexane) at 0°C, cooling removed, stirred until gas evolution had ceased; volatiles removed (vac.), extd. (hexane/diethyl ether), filtered, concd.(vac.), stored (-26°C, several d); elem. anal.;91%
N-ethyl-N-hydroxy-ethanamine
3710-84-7

N-ethyl-N-hydroxy-ethanamine

1,4-dioxaspiro[4.7]dodec-6-yne

1,4-dioxaspiro[4.7]dodec-6-yne

(E)-N,N-diethyl-1,4-dioxaspiro[4.7]dodec-6-en-7-amine oxide

(E)-N,N-diethyl-1,4-dioxaspiro[4.7]dodec-6-en-7-amine oxide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.166667h; Kinetics; Solvent; Inert atmosphere;91%

3710-84-7Relevant articles and documents

Regio- and Enantioselective Formal Hydroamination of Enamines for the Synthesis of 1,2-Diamines

Yu, Lu,Somfai, Peter

supporting information, p. 8551 - 8555 (2019/05/21)

The asymmetric formal hydroamination of enamines using a CuH catalyst is reported. The method provides a straightforward and efficient approach to the synthesis of chiral 1,2-dialkyl amines in good yields with high levels of enantioselectivities for a broad range of substrates, and should have significant value for the preparation of molecules bearing a 1,2-diamine motif.

Selective Oxidation of Secondary Amines to N,N-Disubstituted Hydroxylamines by Choline Peroxydisulfate

Banan, Alireza,Valizadeh, Hassan,Heydari, Akbar,Moghimi, Abolghasem

, p. 2315 - 2319 (2017/10/06)

N,N-Disubstituted hydroxylamines were prepared directly from secondary amines by a reliable method using an oxidizing task-specific ionic liquid, choline peroxydisulfate. The operational simplicity, high selectivity, and green reaction conditions, make this method efficient and practical.

Catalytic method for preparing symmetrical and nonsymmetrical dialkylhydroxylamines

-

, (2008/06/13)

A process of forming N,N-dialkylhydroxylamines (a class of compounds useful as oxygen scavengers in boiler water feed) by contacting an N-alkylhydroxylamine with an alkyl carbonyl compound to form a nitrone in situ or, alternatively, using previously formed alkylnitrone which is subjected to H2 and a hydrogenation catalyst.

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