3717-29-1

Basic information

• Product Name: (E)-3-Nitrobenzaldehyde oxime
• Synonyms: (E)-3-Nitrobenzaldehyde oxime;(E)-N-[(3-nitrophenyl)methylidene]hydroxylamine
• CAS NO: 3717-29-1
• Molecular Formula: C₇H₆N₂O₃
• Molecular Weight: 0
• Mol File: 3717-29-1.mol
• Article Data: 11

Chemical Properties

• Melting Point: 119.0 to 122.0 °C
• Appearance: /
• CAS DataBase Reference: (E)-3-Nitrobenzaldehyde oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-Nitrobenzaldehyde oxime(3717-29-1)
• EPA Substance Registry System: (E)-3-Nitrobenzaldehyde oxime(3717-29-1)

Safety Data

• Hazardous Substances Data: 3717-29-1(Hazardous Substances Data)

Usage

General Description

(E)-3-Nitrobenzaldehyde oxime is a chemical compound with the molecular formula C7H6N2O3. It is an oxime derivative of (E)-3-nitrobenzaldehyde, and is commonly used as an intermediate in the synthesis of various pharmaceuticals, agrochemicals, and dyes. (E)-3-Nitrobenzaldehyde oxime is a yellow crystalline solid with a melting point of 128-130°C, and it is sparingly soluble in water but soluble in organic solvents such as ethanol and acetone. (E)-3-Nitrobenzaldehyde oxime is also known to have potential applications as a reagent in organic synthesis for the formation of carbon-carbon and carbon-nitrogen bonds. It is important to handle this chemical with caution, as it can be harmful if swallowed, inhaled, or in contact with the skin, and may cause irritation to the respiratory system.

Upstream product

• 3848-32-6 3-nitro-benzaldehyde-(O-benzoyl oxime ) 
• 7664-41-7 ammonia 
• 39089-86-6 3-nitro-benzaldehyde-(O-phenylcarbamoyl-seqtrans-oxime ) 
• 7409-18-9 3-nitrobenzylamine 
• 99-61-6 3-nitro-benzaldehyde 
• 3848-31-5 3-nitro-benzaldehyde-((E)-O-acetyl oxime ) 
• 932-90-1 syn-benzaldehyde oxime 
• 109-73-9 N-butylamine 
• 39089-86-6 3-nitro-benzaldehyde-(O-phenylcarbamoyl oxime ) 
• 87-91-2 diethyl (2R,3R)-tartrate 
• 3717-30-4 3-nitrobenzaldoxime 

Downstream Products

• 5346-31-6 3-nitro-benzaldehyde semicarbazone 
• 33499-33-1 (E)-3-nitrobenzaldehyde O-methyloxime 
• 16089-77-3 N-methyl-α-(m-nitrophenyl)nitrone 
• 116081-78-8 m-nitrobenzonitrolic acid 
• 122199-10-4 Bis-(3-nitro-phenyl)-furazan 
• 74229-71-3 3,5-bis(3-nitrophenyl)-1,2,4-oxadiazole 
• 41401-08-5 bis-(3-nitro-benzylidene)-diazoxane-N-oxide 
• 51003-63-5 3,4-bis(3-nitrophenyl)furoxan 
• 33512-94-6 m-nitrobenzhydroxamoyl chloride 
• 3717-30-4 3-nitrobenzaldoxime 
• 645-09-0 3-nitrobenzamide 
• 3848-31-5 3-nitro-benzaldehyde-((E)-O-acetyl oxime ) 
• 1182713-83-2 3-(3-nitrophenyl)-5-[methyl(phenylcarboxylate)]isoxazole 
• 3848-32-6 3-nitro-benzaldehyde-(O-benzoyl oxime ) 

Relevant articles and documents

M-CPBA mediated metal free, rapid oxidation of aliphatic amines to oximes

An efficient, rapid oxidation of various aliphatic amines to oximes using m-CPBA as an oxidant in ethyl acetate is described. High conversion (100%) with >90% oxime selectivity is achieved at room temperature under catalyst-free conditions. Mild reaction conditions along with an easy work up procedure offer lower byproduct formation and high selectivity for oximes in good yield and purity.

A novel and efficient catalytic system including TEMPO/acetaldoxime/InCl3 for aerobic oxidation of primary amines to oximes

A simple and efficient catalytic system including TEMPO/acetaldoxime/InCl3 for aerobic oxidation of primary amines to corresponding oximes by using toluene as the solvent is described. This practical method can use O2 as the economic and green oxidant, tolerate a wide range of substrates, which can afford the target oximes in moderate to excellent yields.

Simple, efficient and green synthesis of oximes under ultrasound irradiation

The condensation of aldehydes andketones with hydroxylamine hydrochloride gives oximes in 81-95%yields in water andEtOH under ultrasound irradiation. Compared to conventional methods, the main advantages of the present procedure are milder reaction conditions, shorter reaction times and higher yields.