37556-51-7

Basic information

• Product Name: Benzenesulfonothioic acid, 4-methyl-, S-cyclohexyl ester
• CAS NO: 37556-51-7
• Molecular Formula: C13H18O2S2
• Molecular Weight: 270.417
• Mol File: 37556-51-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenesulfonothioic acid, 4-methyl-, S-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonothioic acid, 4-methyl-, S-cyclohexyl ester(37556-51-7)
• EPA Substance Registry System: Benzenesulfonothioic acid, 4-methyl-, S-cyclohexyl ester(37556-51-7)

Safety Data

• Hazardous Substances Data: 37556-51-7(Hazardous Substances Data)

Upstream product

• 1569-69-3 Cyclohexanethiol 
• 15223-20-8 1-methyl-4-{[(trifluoromethyl)sulfanyl]sulfonyl}benzene 
• 2550-40-5 1,2-dicyclohexyl disulfide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 28519-50-8 potassium thiotosylate 
• 3753-27-3 sodium 4-methylbenzenesulfonothioate 

Downstream Products

• 1927-56-6 2-(cyclohexylthio)tetrahydrofuran 
• 64495-84-7 Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-cyclohexylsulfanyl-tetrahydro-pyran-3-yl ester 
• 86763-32-8 S-cyclohexyl 4-methoxybenzothioate 
• 39938-31-3 Benzoyl cyclohexyl disulfide 
• 4251-13-2 thiocyanatocyclohexane 
• 19294-29-2 potassium 4-methylbenzenesulfinate 

Relevant articles and documents

Enantioselective Copper-Catalyzed Electrophilic Sulfenylation of Cyclic Imino Esters

Herein we report an enantioselective sulfenylation of cyclic imino esters with the efficient and versatile sulfenylation reagent S-alkyl 4-methylbenzenesulfonothioates. By utilizing the Cu/tBu-Phosferrox catalytic system, we can assemble diverse S-alkyl groups into the cyclic imino esters under mild conditions in good yields and with excellent enantioselectivities. Remarkably, this method demonstrates a high tolerance of diverse functional groups and proves to be applicable in the late-stage functionalization of pharmaceuticals.

TFA promoted multi-component reaction of aryldiazonium with sodium metabisulphite and thiols: Construction of thiosulfonate under transition-metal free conditions

A TFA promoted multi-component reaction of aryldiazonium with sodium metabisulphite and thiols to construct thiosulfonates under transition-metal free conditions is reported. The thiosulfonates were isolated in good yields with broad tolerance of function

Selective Ortho Thiolation Enabled by Tuning the Ancillary Ligand in Palladium/Norbornene Catalysis

Site-selective introduction of a sulfur group into aromatic compounds is essential and useful in organic, material, and pharmaceutical chemistry. A palladium/norbornene-catalyzed chemoselective ortho thiolation of aryl halides was reported. The selectivit