38011-36-8

Basic information

• Product Name: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE
• Synonyms: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE
• CAS NO: 38011-36-8
• Molecular Formula: C₃₆H₃₀NP₂*N₃
• Molecular Weight: 0
• Mol File: 38011-36-8.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE(38011-36-8)
• EPA Substance Registry System: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE(38011-36-8)

Safety Data

• RIDADR: 0473
• HazardClass: 1.1A
• Hazardous Substances Data: 38011-36-8(Hazardous Substances Data)

Upstream product

• 21050-13-5 bis(triphenylphosphine)iminium chloride 

Downstream Products

• 53765-64-3 COFe(P(C₆H₅)3)2(N₂C₆H₄CH₃-p)N₃ 
• 115590-95-9 {(PP₃)RhN₃} 
• 119545-41-4 ((C₆H₅)3P)2N⁽¹⁺⁾*{Os₃(NCO)(CO)11}^(1-)=((C₆H₅)3P)2N{Os₃(NCO)(CO)11} 
• 1347703-26-7 bis(triphenylphosphoranylidene)antimonite tetraazidoarsenite 
• 1415313-15-3 bis(triphenylphosphoranylidene)ammonium tetraazidoarsenite 

Relevant articles and documents

Synthesis of sulfur-rich polymers: Copolymerization of cyclohexene sulfide and carbon disulfide using chromium complexes

An investigation of the copolymerization of cyclohexene sulfide and carbon disulfide using salphen and salen Cr complexes as catalysts and [PPN]+X- salts as cocatalysts, at different temperatures and reaction times, is reported. Both

Kinetic studies of the alternating copolymerization of cyclic acid anhydrides and epoxides, and the terpolymerization of cyclic acid anhydrides, epoxides, and CO2 catalyzed by (salen)CrIIICl

Copolymerization of a series of cyclic acid anhydrides with several epoxides using (salen)CrCl/onium salt catalysts has afforded polyesters with high molecular weights and narrow molecular weight distributions. The (salen)CrCl catalyst in the presence of

Binary polyazides of cadmium and mercury

Following our interest in binary element-nitrogen compounds we report here on the synthesis and comprehensive characterization (M.p., IR/Raman, elemental analysis, 14N/133Cd/199Hg NMR) of tri-and tetraazido cadmate and mercurate anions [E(N3)(2+n)]n- (E = Cd, Hg; n = 1, 2) in a series of [Ph4P]+ and [PNP]+ ([PNP]+ = bis(triphenylphosphine)-iminium) salts. The azide/chloride exchange in CH2Cl2 as well as the formation of tetrazolate salts in CH3CN solutions of the polyazido mercurates were investigated. Single crystal X-ray structures of all new compounds, and for comparison [Ph4P][Cd2(N3)5(H2O)], were determined. Moreover, the synthesis of anhydrous cadmium(II) azide and its DMSO adduct is presented for the first time. For a better understanding of structure and bonding in E(N3)2, [E(N3)3]- and [E(N3)4]2-, theoretical calculations at the M06-2X/aug-cc-pVDZ level were carried out.