38011-83-5

Basic information

• Product Name: Benzene, 1-[(3E)-4,8-dimethyl-3,7-nonadienyl]-4-methoxy-
• Synonyms: (3E)-4,8-dimethyl-1-(4-methoxyphenyl)-3,7-nonadiene;(E)-4-homogeranylphenyl methyl ether;Benzene,1-[(3E)-4,8-dimethyl-3,7-nonadienyl]-4-methoxy;(6E)-9-p-Methoxyphenyl-2,6-dimethylnona-2,6-diene;(E)-4-homogeranylanisole;4-homogeranylanisole;Benzene,1-(4,8-dimethyl-3,7-nonadienyl)-4-methoxy
• CAS NO: 38011-83-5
• Molecular Formula: C18H26O
• Molecular Weight: 258.404
• Mol File: 38011-83-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(3E)-4,8-dimethyl-3,7-nonadienyl]-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(3E)-4,8-dimethyl-3,7-nonadienyl]-4-methoxy-(38011-83-5)
• EPA Substance Registry System: Benzene, 1-[(3E)-4,8-dimethyl-3,7-nonadienyl]-4-methoxy-(38011-83-5)

Safety Data

• Hazardous Substances Data: 38011-83-5(Hazardous Substances Data)

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 106-24-1 Geraniol 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 38769-92-5 4-methoxybenzylmagnesium chloride 
• 623-12-1 4-chloromethoxybenzene 
• 425681-14-7 diethyl ((E)-4,8-dimethyl-3,7-nonadienyl)phosphonate 
• 60699-32-3 (E)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate 
• 6138-90-5 trans-geranyl bromide 
• 35162-74-4 geranyl phenyl sulfide 

Downstream Products

• 10064-08-1 (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene 
• 303962-71-2 (4aR,10aR)-1,2,3,4,4a,9,10,10a-Octahydro-6-methoxy-1,1,4a-trimethylphenanthrene 
• 269719-13-3 3-(4-methoxyphenylethyl)-2,4,4-trimethyl-1-cyclohexene 
• 83999-80-8 (E)-9-(4-Methoxy-phenyl)-2,6-dimethyl-nona-1,6-dien-3-ol 
• 83999-79-5 ((1S,2S,4aR,10aS)-2-Benzyloxy-6-methoxy-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthren-1-yl)-methanol 
• 511-05-7 sugiol 
• 514-62-5 (+/-)-ferruginol 
• 106625-40-5 4-((E)-4,8-Dimethyl-nona-3,7-dienyl)-1,2-dimethoxy-benzene 
• 1252599-38-4 C₁₈H₂₆O₂ 
• 709667-29-8 C₁₈H₂₇BrO₂ 
• 425681-12-5 (E)-3-homogeranyl-4-(tert-butyldiphenylsilyloxy)benzene 
• 331233-75-1 (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)phenol 

Relevant articles and documents

Scalable Total Synthesis of rac-Jungermannenones B and C

Reported is the first scalable synthesis of rac-jungermannenones B and C starting from the commercially available and inexpensive geraniol in 10 and 9 steps, respectively. The unique jungermannenone framework is rapidly assembled by an unprecedented regio

Practical and Efficient Strategy for Synthesis of Ferruginol, Sugiol, and Sugiol Methyl Ether from Geraniol

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Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

A sulfenium-ion-initiated, catalytic, enantioselective polyene cyclization is described. Homogeranylarenes and ortho-geranylphenols undergo polycyclization in good yield, diastereoselectivity, and enantioselectivity. The stereodetermining step is the generation of an enantiomerically enriched thiiranium ion from a terminal alkene and a sulfenylating agent in the presence of a chiral Lewis basic catalyst. The use of hexafluoroisopropyl alcohol as the solvent is crucial to obtain good yields. The thioether moiety resulting from the reaction can be subsequently transformed into diverse oxygen and carbon functionality postcyclization. The utility of this method is demonstrated by the enantioselective syntheses of (+)-ferruginol and (+)-hinokiol.