38474-09-8

Basic information

• Product Name: 4-(anthracen-9-yl)-N,N-dimethylaniline
• CAS NO: 38474-09-8
• Molecular Formula: C₂₂H₁₉N
• Molecular Weight: 297.393
• Mol File: 38474-09-8.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 458.4°C at 760 mmHg
• Flash Point: 183.4°C
• Density: 1.139g/cm³
• Vapor Pressure: 1.37E-08mmHg at 25°C
• Refractive Index: 1.699
• CAS DataBase Reference: 4-(anthracen-9-yl)-N,N-dimethylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(anthracen-9-yl)-N,N-dimethylaniline(38474-09-8)
• EPA Substance Registry System: 4-(anthracen-9-yl)-N,N-dimethylaniline(38474-09-8)

Safety Data

• Hazardous Substances Data: 38474-09-8(Hazardous Substances Data)

Upstream product

• 46491-50-3 9,19-Dibromo-9,10-dihydroanthracene 
• 67-66-3 chloroform 
• 121-69-7 N,N-dimethyl-aniline 
• 90-44-8 anthracen-9(10H)-one 
• 7353-91-5 4-dimethylaminophenylmagnesium bromide 
• 1564-64-3 9-Bromoanthracene 
• 28611-39-4 4-(dimethylamino)benzene-boronic acid 
• 523-27-3 9,10-Dibromoanthracene 
• 25882-75-1 9-<4-(N,N-dimethylamino)phenyl>-9,10-dihydroanthracene 

Relevant articles and documents

Erratum: Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type PdIV intermediates (Dalton Transactions (2011) 40 (8996) DOI: 10.1039/C1DT10398A)

-

Anthracenylporphyrins

We report the synthesis and characterization of meso-anthracenylporphyrins with zinc and nickel metal centers. A variety of novel aryl and alkyl meso-substituted anthracenylporphyrins were synthesized via step-wise Suzuki cross-coupling reactions using an

Photochemical Reactions of Aromatic Compounds. XXXVI. The Photoreactions of Anthracene with Some Selected Tertiary Aromatic Amines in Polar Media

The photoreaction of anthracene witn N,N-dimethylaniline in acetonitrile gave 9-(p-dimethylaminophenyl)-9,10-dihydroanthracene in a good yield, along with 9,10-dihydroanthracene and 9,9',10,10'-tetrahydro-9,9'-bianthryl.This photoreaction was found to depend on the polarity of the solvent as well as on its protic or aprotic nature.With N,N-dimethyl-m-toluidine, a similar 1 : 1 adduct was obtained, while the reduced anthracenes were mainly formed in the photoreactions with N,N-dimethyl-o- and p-toluidines.The mechanisms were discussed in terms of the dissociation into the ion radical as well as their reactivities.