384793-29-7Relevant articles and documents
Visible-Light-Triggered C-C and C-N Bond Formation by C-S Bond Cleavage of Benzylic Thioethers
Lanzi, Matteo,Merad, Jérémy,Boyarskaya, Dina V.,Maestri, Giovanni,Allain, Clémence,Masson, Géraldine
supporting information, p. 5247 - 5250 (2018/09/13)
The cleavage of sulfidic C-S bonds under visible-light irradiation was harnessed to generate carbocations under neutral conditions and synthesize valuable di- and triarylalkanes as well as benzyl amines. To this end, photoredox catalysis and direct photoinduced C-S bond cleavage are used as complementary approaches and participate in the versatility of the general strategy. Extensive mechanistic studies have demonstrated the diversity of the reaction mechanism at work in these different reactions.
A straightforward entry to γ-trifluoromethylated allenamides and their synthetic applications
Guissart, Céline,Dolbois, Aymeric,Tresse, Cédric,Saint-Auret, Sarah,Evano, Gwilherm,Blanchard, Nicolas
supporting information, p. 2575 - 2580 (2016/11/11)
γ-Trifluoromethylated allenamides were obtained in good to excellent yields through a base-induced isomerization from the corresponding protected trifluoromethylated propargylic amines. This method, which simply required the treatment of the starting prop
Synthesis of an alkylidene 2-oxazolidinone via gold-catalyzed cyclization of a N-boc-allenylaniline
De Sousa Fonseca, Flavia C.,Araujo, Flavia M.,Nagem, Tanus J.,De Oliveira, Tania T.,Roque D. Correia, Carlos,Taylor, Jason G.
, p. 768 - 773 (2013/01/15)
N-Boc-allenylaniline undergoes cyclization in the presence of a catalytic amount of a cationic gold complex to exclusively form 2-oxazolidinones, whereas the N-Moc-allenylaniline affords dihydroquinolines. Supplemental materials are available for this art
