3883-55-4Relevant articles and documents
Extended conjugation in enynones, dienones and related species: A theoretical and experimental study. the molecular structures of 3-ethynyl-2-methylcyclopent-2-enone, 3-ethenyl-2-methylcyclopent-2-enone and 3-ethyl-2-methylcyclopent-2-enone, as studied by
Traetteberg, Marit,Liebman, Joel F.,Hulce, Martin,Bonn, Anthony A.,Rogers, Donald W.
, p. 1925 - 1932 (2007/10/03)
The molecular structures of three 3-R substituted conjugated enones have been determined by the gas electron difraction method. Depending on the nature of the substituents the molecules represent examples of molecules with no additional conjugation, relat
New chemistry of cyclic, s-trans-enaminones: Addition of Grignard reagents to enaminones derived from 2-methylcyclohexane-1,3-dione
Shawe, Thomas T.,Landino, Linda M.,Ross, Andrew A.,Prokopowicz, Anthony S.,Robinson, Patrice M.,Cannon, Annatina
, p. 3823 - 3824 (2007/10/03)
Grignard reagents add to cyclic s-trans enaminones to give the cycloalkenone after aqueous hydrolysis. In some cases a competitive double addition takes place. These reactions have been found to be solvent- and reagent-selective.