3944-07-8

Basic information

• Product Name: 1-benzyl-1-methylsilacyclobutane
• Synonyms: 1-benzyl-1-methylsilacyclobutane
• CAS NO: 3944-07-8
• Molecular Weight: 176.334
• Mol File: 3944-07-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-benzyl-1-methylsilacyclobutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzyl-1-methylsilacyclobutane(3944-07-8)
• EPA Substance Registry System: 1-benzyl-1-methylsilacyclobutane(3944-07-8)

Safety Data

• Hazardous Substances Data: 3944-07-8(Hazardous Substances Data)

Upstream product

• 7787-93-1 dichloro(3-chloropropyl)methylsilane 
• 100-39-0 benzyl bromide 
• 2351-34-0 1-chloro-1-methylsiletane 

Downstream Products

• 325461-96-9 1-methylene-6-(1-methylsilacyclobutyl)-2,4-cyclohexadiene 

Relevant articles and documents

Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes

A Rh-catalyzed reaction of silacyclobutanes (SCBs) with unactivated alkynes has been developed to form silacyclohexenes with high chemoselectivity. Good enantioselectivity at the stereogenic silicon center was achieved using a chiral phosphoramidite ligand. The resulting silacyclohexenes are useful scaffolds for synthesizing structurally attractive silacyclic compounds.