39652-06-7

Basic information

• Product Name: benzenetellurinyl acetate
• Synonyms: benzenetellurinyl acetate
• CAS NO: 39652-06-7
• Molecular Weight: 279.75
• Mol File: 39652-06-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: benzenetellurinyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzenetellurinyl acetate(39652-06-7)
• EPA Substance Registry System: benzenetellurinyl acetate(39652-06-7)

Safety Data

• Hazardous Substances Data: 39652-06-7(Hazardous Substances Data)

Upstream product

• 32294-60-3 diphenyl ditelluride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 94971-86-5 benzenetellurinic acid anhydride 
• 64-19-7 acetic acid 
• 108-24-7 acetic anhydride 

Downstream Products

• 122823-60-3 C₁₃H₁₆O₂Te 
• 122823-57-8 2,3-dihydro-2-<(phenyltelluro)methyl>benzofuran 
• 39510-74-2 methyl α,χ-diphenylallophanate 
• 102-07-8 bis(diphenyl)urea 
• 112476-13-8 ethyl <2-(phenyltelluro)hexadecyl>carbamate 
• 112476-41-2 ethyl <1-<(phenyltelluro)methyl>pentadecyl>carbamate 
• 112476-39-8 ethyl <1-<(phenyltelluro)methyl>pentyl>carbamate 
• 112476-40-1 ethyl <2-(phenyltelluro)hexyl>carbamate 
• 112476-15-0 ethyl <3-phenyl-2-(phenyltelluro)propyl>carbamate 
• 112476-14-9 ethyl <2-phenyl-1-<(phenyltelluro)methyl>ethyl>carbamate 
• 112476-38-7 ethyl <1-phenyl-2-(phenyltelluro)ethyl>carbamate 

Relevant articles and documents

Hypervalent iodine in synthesis XXVIII: The preparation and utility of polymer-supported phenyliodine(III) diacetate

The polymer-supported phenyliodine(III) diacetate has been developed, which has been used effectively to oxidize a variety of organic compounds with good yield.

Cyclofunctionalization of Hydroxyolefins Induced by Arenetellurinyl Acetate

Treatment of arenetellurinic anhydride (1) with acetic acid or anhydride readily formed arenetellurinyl acetate (2).It underwent not only oxytellurinylation of an olefin but also intramolecular cyclofunctionalization of various hydroxyolefins to cyclic ethers.The latter reaction was effectively accelerated by addition of boron trifluoride etherate or tin(IV) chloride and highly regio- and stereoselective.The tellurium functional group introduced in the cyclic ethers could be manipulated into other versatile groups by telluroxide elimination, halogenolysis, and reductive detelluration.

CYCLOFUNCTIONALIZATION OF HYDROXYOLEFINS INDUCED BY ARENETELLURINIC ANHYDRIDE

Arenetellurinic anhydride reacts with hydroxyolefins in acetic acid at reflux to give cyclic ethers bearing a phenyltelluro group.A mechanism via intramolecular oxytellurinylation with arenetellurinyl acetate is proposed.