3973-17-9Relevant articles and documents
Primary Alcohols via Nickel Pentacarboxycyclopentadienyl Diamide Catalyzed Hydrosilylation of Terminal Epoxides
Lambert, Tristan H.,Steiniger, Keri A.
supporting information, p. 8013 - 8017 (2021/10/25)
The efficient and regioselective hydrosilylation of epoxides co-catalyzed by a pentacarboxycyclopentadienyl (PCCP) diamide nickel complex and Lewis acid is reported. This method allows for the reductive opening of terminal, monosubstituted epoxides to form unbranched, primary alcohols. A range of substrates including both terminal and nonterminal epoxides are shown to work, and a mechanistic rationale is provided. This work represents the first use of a PCCP derivative as a ligand for transition-metal catalysis.
ACETONITRILE DERIVATIVE, PEST CONTROL AGENT, AND METHOD OF USING THE SAME
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Page/Page column 81-82, (2010/11/08)
An acetonitrile derivative represented by the general formula (I): (I) (wherein A represents (VV) or (WW) B represents (XX) (YY) or (ZZ) and R represents hydrogen, C1-6 alkyl, etc. (Q1, Q2, Ar1, and Ar2 each represents phenyl, substituted phenyl, etc.; R1, R2, R3, R4, R6, R7, and R8 each represents hydrogen, C1-6 alkyl, etc.; R5 represents C1-6 alkyl, etc.; G represents NR10, etc.; W represents O, S, NR9, etc.; R9 and R10 each represents hydrogen, etc.; and n is an integer of 0-4)). The acetonitrile derivative is remarkably active in controlling pests even when used in a small dose. It is useful as an agricultural or horticultural bactericide or an animal parasite control agent.