39761-61-0

Basic information

• Product Name: 5,5-Dimethyl-,(Z)-2-Hexene
• Synonyms: 5,5-Dimethyl-,(Z)-2-Hexene;(Z)-5,5-Dimethyl-2-hexene
• CAS NO: 39761-61-0
• Molecular Formula: C8H16
• Molecular Weight: 112.2126
• Mol File: 39761-61-0.mol
• Article Data: 2

Chemical Properties

• Melting Point: -103.01°C (estimate)
• Boiling Point: 120.2°C (estimate)
• Flash Point: 8.4°C
• Appearance: /
• Density: 0.7125
• Vapor Pressure: 36.3mmHg at 25°C
• Refractive Index: 1.4088
• CAS DataBase Reference: 5,5-Dimethyl-,(Z)-2-Hexene(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-Dimethyl-,(Z)-2-Hexene(39761-61-0)
• EPA Substance Registry System: 5,5-Dimethyl-,(Z)-2-Hexene(39761-61-0)

Safety Data

• Hazardous Substances Data: 39761-61-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H16/c1-5-6-7-8(2,3)4/h5-6H,7H2,1-4H3/b6-5-

Upstream product

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• 594-19-4 tert.-butyl lithium 
• 106-99-0 buta-1,3-diene 
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• 73062-97-2 ethyl 1-but-3-en-1-ylcyclohexanecarboxylate 
• 110362-46-4 (E)-4-phenylsulfonyl-2,2-dimethyl-4-hexene 
• 77400-57-8 5-(iodomethyl)-5-methyl-1-hexene 
• 56068-49-6 2,2-dimethyl-1-bromo-5-hexene 
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• 4784-77-4 (E)-1-Bromo-2-butene 
• 31841-77-7 5,5-dimethylhexan-2-ol 
• 690-93-7 (E)-2,2-dimethyl-3-hexene 

Downstream Products

• 127782-54-1 4-Phenyl-1-((E)-1,4,4-trimethyl-pent-2-enyl)-[1,2,4]triazolidine-3,5-dione 

Relevant articles and documents

AN EASY SYNTHESIS OF THE 2-PHENYLSULFONYL-SUBSTITUTED ALLYLIC BROMIDES AND ACETATES AND THEIR REACTIVITY TOWARDS NUCLEOPHILES

The reaction of phenyl vinyl sulfone with various aldehydes in the presence of a catalytic amount of DABCO furnishes in good yields the corresponding 2-phenylsulfonyl-substituted alcohols 5a-5e which can be easily converted into their acetates 2a-2b or into their allylically rearranged bromides 3a-3d.These reagents, in turn, react with nucleophiles (ketone enolates and cuprates) with an allylic rearrangement (SN2' mechanism) to give the functionalized unsaturated sulfones 6a-g and 7a-g.A palladium catalyzed reaction allows a stereo-controlled transformation of the sulfone 6b into the (Z,Z) skipped 1,4-diene 8.