40098-26-8

Basic information

• Product Name: METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE
• Synonyms: METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE;1-Cyclopentene-1-heptanoic acid, 3-hydroxy-5-oxo-, Methyl ester;Methyl-3-hydroxy-5-oxo-1-cyclopentene-1-heptanoate;1-Cyclopentence-1-heptanoic acid,3-hydroxy-5oxo-,methy ester;Methyl 7-(3-hydroxy-5-oxocyclopent-1-en-1-yl)heptanoate
• CAS NO: 40098-26-8
• Molecular Formula: C₁₃H₂₀O₄
• Molecular Weight: 240.3
• Mol File: 40098-26-8.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 378.4±42.0 °C(Predicted)
• Appearance: /
• Density: 1.125
• Storage Temp.: 2-8°C
• PKA: 12.95±0.40(Predicted)
• CAS DataBase Reference: METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE(40098-26-8)
• EPA Substance Registry System: METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE(40098-26-8)

Safety Data

• Hazardous Substances Data: 40098-26-8(Hazardous Substances Data)

Usage

Uses

Methyl 7-[(3RS)-3-Hydroxy-5-oxocyclopent-1-enyl]heptanoate is a reagent used in the synthesis of naturally occuring prostaglandins and congeners.

Upstream product

• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 
• 77188-70-6 3-chloro-4-cyclopent-2-enone 
• 101650-79-7 methyl 8-(2-furyl)-8-hydroxy-octanoate 
• 98818-31-6 methyl 7-(2-hydroxy-5-oxocyclopent-3-enyl)heptanoate 
• 98736-11-9 9-((1S,2R,3S)-2,3-Dimethoxy-cyclopropyl)-9-oxo-nonanoic acid methyl ester 
• 71120-92-8 2-(6'-methoxycarbonylhexyl)-4-bromocyclopent-2-enone 
• 40098-24-6 2-(6-methoxycarbonylhexyl)-4-(tetrahydropyran-2-yloxy)cyclopent-2-enone 
• 67-56-1 methanol 
• 5239-43-0 7-(5-oxo-1-cyclopenten-1-yl)heptanoic acid 
• 32561-42-5 methyl 2-methoxy-4-hydroxy-5-oxocyclopent-1-eneheptanoate 
• 61369-17-3 8-Methylsulfanyl-9-oxo-decanoic acid methyl ester 
• 51534-42-0 1-methylsulfanyl-1-methylsulfinylethylene 
• 34546-57-1 2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one 
• 144-55-8 sodium hydrogencarbonate 

Downstream Products

• 59122-46-2 misoprostol 
• 41138-69-6 7-{3-[(tert-butyldimethylsilanyl)oxy]-5-oxocyclopent-1-en-1-yl}heptanoic acid methyl ester 
• 41138-61-8 (4R)-4-hydroxy-2-(6-methoxycarbonylhexyl)cyclopent-2-enone 
• 42038-75-5 methyl 7-<3(S)-(hydroxy)-5-oxo-1-cyclopenten-1-yl>heptanoate 
• 127126-27-6 methyl 7-<3(R)-(acetyloxy)-5-oxo-1-cyclopenten-1-yl>heptanoate 
• 40098-24-6 2-(6-methoxycarbonylhexyl)-4-(tetrahydropyran-2-yloxy)cyclopent-2-enone 
• 58682-80-7 misoprostol 
• 3434-33-1 prostaglandin E₁ methyl ester 

Relevant articles and documents

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New synthesis of (±)-4-Hydroxy-2-(6-methoxycarbonylhexyl)-2-cyclopentenone

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Synthesis of (±)-15-thia-15-deoxy-PGE1 methyl ester

The 15-thia-15-deoxy analogue of prostaglandin E1 methyl ester has been prepared by the zirconocene chloride mediated conjugate addition of an n-pentyl ethynyl sulfide derived anion to an appropriately substituted cyclopentenone. Similar methodology has also been used to prepare other 3-(3'-thia-1'-octenyl)-cyclopentanones.