4026-27-1

Basic information

• Product Name: 1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOPYRANOSE
• Synonyms: 6-DEOXY-1:2,3:4-DI-O-ISOPROPYLIDENE-ALPHA-D-GALACTOPYRANOSE;1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOPYRANOSE;1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOSE;1:2,3:4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOSE;6-Deoxy-1,2:3,4-di-o-isopropylidene-alpha-D-galactopyranoside;1,2,3,4-Di-O-isopropylidene-a-D-fucopyranose;6-Deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside;1,2,3,4-Diisopropylidene-a-D-Fucopyranose
• CAS NO: 4026-27-1
• Molecular Formula: C₁₂H₂₀O₅
• Molecular Weight: 244.28
• Mol File: 4026-27-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 285.665 °C at 760 mmHg
• Flash Point: 108.939 °C
• Appearance: /
• Density: 1.076 g/cm³
• CAS DataBase Reference: 1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOPYRANOSE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOPYRANOSE(4026-27-1)
• EPA Substance Registry System: 1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOPYRANOSE(4026-27-1)

Safety Data

• Hazardous Substances Data: 4026-27-1(Hazardous Substances Data)

Usage

Uses

6-Deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose is an potential compound used for the synthesis of novel enzyme substrate for β-D-fucosidase.

Upstream product

• 4478-43-7 (1,2:3,4-di-O-isopropylidene-6-O-(p-toluensulfonate))-D-galactopiranose 
• 4148-55-4 (-)-1,2:3,4-di-O-isopropylidene-6-O-methylsulfonyl-α-D-galactopyranose 
• 79233-84-4 6-O-(imidazolylthiocarbonyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 4026-28-2 1,2:3,4-di-O-isopropylidene-6-iodo-D-galactopyranose 
• 94-36-0 dibenzoyl peroxide 
• 75717-36-1 ethyl (Z)-3-(phenylsulfanyl)propenoate 
• 91-22-5 quinoline 

Downstream Products

• 156769-29-8 1-O-acetyl-2,3,4-tri-O-benzyl-α-D-fucopyranose 
• 6422-34-0 rhodeonic acid 
• 28553-11-9 fucose 1-phosphate 
• 1220051-66-0 2-azidoethyl (2,3,5,6-tetra-O-acetyl-β-D-galactofuranosyl)-(1->3)-[(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1->2)]-4-O-acetyl-α-D-fucopyranoside 
• 1220051-64-8 2-azidoethyl (2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1->2)-4-O-acetyl-α-D-fucopyranoside 
• 1220051-61-5 2-azidoethyl (2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1->2)-3,4-O-isopropylidene-α-D-fucopyranoside 
• 119824-72-5 C₂₁H₂₁⁽²⁾HO₆ 

Relevant articles and documents

Reactivity of Carbohydrate Radicals Derived from Iodo Sugars and Dibenzoyl Peroxide. Homolytic Heteroaromatic and Aromatic Substitution, Reduction, and Oxidation

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Some Studies on Proximal Addition-Elimination Procedures in Intermolecular Carbon-Carbon Bond-forming Free Radical Reacttions. Convenient Synthesis of Ethyl (E)-(Ethyl 2,3,6,7,8-Pentadeoxy-α-D-erythro-nona-2,7-dienopyranosid)uronate

Et3B-induced hydrostannation of ethyl propiolate with tributyltin hydride afforded a mixture of ethyl (Z)- and (E)-3-(tributyltin)propenoate which, after purification, could be used as such in radical carbon-carbon bond-forming reactions with iodides as t

Synthesis of Deoxy Sugars. Deoxygenation by Treatment with N,N'-Thiocarbonyldiimidazole/Tri-n-butylstannane

Protected sugars containing a free hydroxyl group have been deoxygenated by conversion to the O-(imidazolylthiocarbonyl) derivative with N,N'-thiocarbonyldiimidazole followed by treatment with tri-n-butylstannane.This reaction sequence offers a mild, high-yield procedure for the deoxygenation of hexose derivatives with a hindered secondary hydroxyl group at C-3 or C-4.The primary 6-O-(imidazolylthiocarbonyl) compound obtained from 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose reacts with tri-n-butylstannane to give a mixture of the 6-deoxy sugar (31percent) and starting alcohol (57percent).