402831-58-7

Basic information

• Product Name: phenyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside
• Synonyms: phenyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside
• CAS NO: 402831-58-7
• Molecular Weight: 385.444
• Mol File: 402831-58-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: phenyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside(402831-58-7)
• EPA Substance Registry System: phenyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside(402831-58-7)

Safety Data

• Hazardous Substances Data: 402831-58-7(Hazardous Substances Data)

Upstream product

• 402831-53-2 phenyl 2-azido-3,4,6-tri-O-acetyl-2-deoxy-1-thio-α-D-mannopyranoside 
• 139066-49-2 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-α/β-D-mannopyranose 
• 97604-58-5 2-azido-2-deoxy-D-mannopyranose 
• 4710-95-6 D-mannosamine hydrochloride 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 166516-71-8 phenyl 2-azido-2-deoxy-1-thio-α-D-mannopyranoside 

Downstream Products

• 402831-61-2 phenyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside 

Relevant articles and documents

Synthesis of staphylococcus aureus type 5 trisaccharide repeating unit: Solving the problem of lactamization

The chemical synthesis of an orthogonally protected trisaccharide derived from the polysaccharide of Staphylococcus aureus Type 5, which is an attractive candidate for the development of immunotherapies, is described. The challenging α-fucosylation and β-mannosylation are addressed through the careful choice of protecting groups. Lactamization of a β-d-ManpNAcA moiety during deprotection was avoided by a late stage oxidation approach. Versatility of the trisaccharide was demonstrated by its transformation into a spacer-containing repeating unit suitable for immunological investigations.