405-84-5

Basic information

• Product Name: Acetic acid, trifluoro-, (4-nitrophenyl)methyl ester
• CAS NO: 405-84-5
• Molecular Formula: C9H6F3NO4
• Molecular Weight: 249.146
• Mol File: 405-84-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, trifluoro-, (4-nitrophenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, trifluoro-, (4-nitrophenyl)methyl ester(405-84-5)
• EPA Substance Registry System: Acetic acid, trifluoro-, (4-nitrophenyl)methyl ester(405-84-5)

Safety Data

• Hazardous Substances Data: 405-84-5(Hazardous Substances Data)

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 347-89-7 benzoic trifluoroacetic anhydride 
• 407-25-0 trifluoroacetic anhydride 

Downstream Products

• 226894-80-0 [Pd(PMe₃)2(OOCCF₃)(CH₂C₆H₄-p-NO₂)] 
• 1388792-45-7 (S)-2-(p-nitrobenzyl)-2,5-dihydrofuran 
• 226895-22-3 [Pd(PMePh₂)2(OOCCF₃)(CH₂C₆H₄-p-NO₂)] 

Relevant articles and documents

Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands

We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed reaction. The reaction is compatible with polar functional groups and can be readily scaled up. Several cyclic olefins worked well as olefin components. Thirty-one examples are included.