40576-90-7

Basic information

• Product Name: 2-(Cyclohexylidenaminothio)benzothiazol
• Synonyms: 2-(Cyclohexylidenaminothio)benzothiazol
• CAS NO: 40576-90-7
• Molecular Weight: 262.4
• Mol File: 40576-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(Cyclohexylidenaminothio)benzothiazol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Cyclohexylidenaminothio)benzothiazol(40576-90-7)
• EPA Substance Registry System: 2-(Cyclohexylidenaminothio)benzothiazol(40576-90-7)

Safety Data

• Hazardous Substances Data: 40576-90-7(Hazardous Substances Data)

Upstream product

• 149-30-4 2-thioxo-3H-1,3-benzothiazole 
• 185-80-8 1-oxa-2-azaspiro[2.5]octane 
• 108-94-1 cyclohexanone 
• 149-30-4 2-Mercaptobenzothiazole 

Downstream Products

• 58890-25-8 1.1'--bis-<3-cyclohexyl>-harnstoff 
• 94091-13-1 1-Cyclohexyl-3-<3-isocyanato-p-tolyl>-harnstoff 
• 154266-51-0 2-(2-Iminocyclohexylthio)benzothiazol 
• 95-33-0 N-(cyclohexyl)benzothiazole-2-sulfenamide 

Relevant articles and documents

A Rearrangement of S-Substituted Cyclohexanone Thioximes

Mercaptoheterocycles like 2-mercaptobenzazoles 5, 2-mercaptouracils 10, and ketene S,S-acetals 18 are aminated by 1-oxa-2-azaspirooctane (1).The intermediate cyclohexanone thioximes, which can be isolated in some cases (6a-c, 11), undergo a 1,3-shift of the mercapto fragment from the nitrogen to the carbon atom followed by cyclization and/or hydrolysis.Thus, new heterocyclic systems as 14-17 or 19 can be created. - Key Words: Aminations / 1-Oxa-2-azaspirooctane / Thioximes / Benzazoles / 2-Thiouraciles