4067-83-8

Basic information

• Product Name: Benzo[f]quinoline, 3-phenyl-
• CAS NO: 4067-83-8
• Molecular Formula: C19H13N
• Molecular Weight: 255.319
• Mol File: 4067-83-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzo[f]quinoline, 3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzo[f]quinoline, 3-phenyl-(4067-83-8)
• EPA Substance Registry System: Benzo[f]quinoline, 3-phenyl-(4067-83-8)

Safety Data

• Hazardous Substances Data: 4067-83-8(Hazardous Substances Data)

Upstream product

• 2579-22-8 Phenylpropargyl aldehyde 
• 91-59-8 naphthalen-2-ylamine 
• 17104-69-7 5,6-benzoquinoline N-oxide 
• 69139-03-3 2-cyano-5,6-benzoquinoline N-oxide 
• 16169-88-3 1-phenylprop-2-ynyl acetate 
• 100-52-7 benzaldehyde 
• 872-36-6 vinylene carbonate 
• 891-32-7 benzylidene(2-naphthyl)amine 
• 85-02-9 benzo[f]quinoline 
• 1078-58-6 diphenylzinc 
• 591-51-5 phenyllithium 
• 111-34-2 -butyl vinyl ether 
• 18125-24-1 benzo[f]quinoline-3-carbonitrile 
• 860560-23-2 2-benzoyl-3-phenyl-benzo[f]quinoline-1-carboxylic acid 

Relevant articles and documents

Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines

Here we report a novel Rh-catalyzed C-H/C-H alkenylation of N-arylmethanimines with vinylene carbonate acting as a vinylene unit. Forty examples of C3,C4-nonsubstituted quinolines were achieved from commercially available starting materials. This identified process features an exceedingly simple system, a lower loading of catalyst, and the capacity for postfunctionalization with bioactive molecules.

Synthesis of quinolines through copper-catalyzed intermolecular cyclization reaction from anilines and terminal acetylene esters

A simple and convenient copper-catalyzed intermolecular cyclization reaction for the synthesis of quinolines from anilines and terminal acetylene esters has been developed. This methodology constructs the C-N and C-C bonds successively via a cascade process, and provides the desired products in moderate to good yields.

Catalytic arylation of a C-H bond in pyridine and related six-membered N-heteroarenes using organozinc reagents

Despite significant advances in the catalytic direct arylation of heteroarenes, the application of this reaction to pyridines has been met with limited success. An oxidative nucleophilic arylation strategy has been developed to overcome this problem. Pyridine, pyrazine, quinolone, and related electron-deficient N-heteroarenes can be arylated at the most electrophilic site using the developed nickel-catalyzed reaction. This protocol serves as a complementary method to catalytic direct arylation reactions. Less is more: Pyridine, pyrazine, quinoline and related electron-deficient N-heteroarenes can be arylated at the most electrophilic site using organozinc reagents through nickel catalysis. This protocol serves as a complementary method to catalytic direct arylation reactions. Copyright