4070-01-3Relevant articles and documents
Free Radicals as Clathrate Hosts: Crystal and Molecular Structure of 1:1 Perchlorotriphenylmethyl Radical-Benzene
Veciana, Jaume,Carilla, Josep,Miravitlles, Carlos,Molins, Elies
, p. 812 - 814 (1987)
The perchlorotriphenylmethyl radical (2) acts as a clathrate host forbenzene, halogenobenzenes, and 1,4-dioxane giving inclusion compounds with different stabilities; the structure of (2)-C6H6, established by X-ray diffraction, shows the guest molecules l
Oxidation of the perchlorotriphenylmethyl radical to the carbocation, and its unique abrupt reversion
Ballester, Manuel,Miravitlles, Carlos,Molins, Elies,Carreras, Conxita
, p. 2748 - 2751 (2007/10/03)
A solution of AlCl3 in CH2Cl2 reacts slowly, at room temperature, with perchlorotriphenylmethyl radical (PTM.), an inert carbon free radical, to give perchlorotriphenylmethyl cation (PTM+) quantitativ
Unique Single-Electron Transfers between Chemically Inert Triphenylmethyl Radicals and Triphenylmethyl Anions
Ballester, Manuel,Pascual, Isabel,Torres, Josep
, p. 3035 - 3044 (2007/10/02)
A number of SET reactions between inert 4-X-tetradecachlorotriphenylmethyl radicals (X-PTM.) and stable tetra-n-butylammonium (Q+) 4-Y-tetradecachlorotriphenylmethides (Q+ Y-PTM:-; X,Y= H, Me, NH2CO, Me2NCO, Ph2