4071-58-3

Basic information

• Product Name: 2-METHYL-2-(3-OXO-BUTYL)-CYCLOHEXANONE
• Synonyms: 2-METHYL-2-(3-OXO-BUTYL)-CYCLOHEXANONE
• CAS NO: 4071-58-3
• Molecular Formula: C₁₁H₁₈O₂
• Molecular Weight: 182.25942
• Mol File: 4071-58-3.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 276.7°C at 760 mmHg
• Flash Point: 102.8°C
• Appearance: /
• Density: 0.963g/cm³
• Vapor Pressure: 0.00472mmHg at 25°C
• Refractive Index: 1.452
• CAS DataBase Reference: 2-METHYL-2-(3-OXO-BUTYL)-CYCLOHEXANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYL-2-(3-OXO-BUTYL)-CYCLOHEXANONE(4071-58-3)
• EPA Substance Registry System: 2-METHYL-2-(3-OXO-BUTYL)-CYCLOHEXANONE(4071-58-3)

Safety Data

• Hazardous Substances Data: 4071-58-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 629, 1984Tetrahedron Letters, 20, p. 3489, 1979 DOI: 10.1016/S0040-4039(01)95442-5

InChI:InChI=1/C11H18O2/c1-9(12)6-8-11(2)7-4-3-5-10(11)13/h3-8H2,1-2H3

Upstream product

• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 
• 67935-23-3 trans-3-methoxybut-2-en-1-ol 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 
• 78-94-4 methyl vinyl ketone 
• 20152-33-4 1-tert-butyldimethylsilyloxy-2-methyl-1-cyclohexene 
• 127939-06-4 2-(trans-but-2-enyl)-2-methylcyclohexanone semicarbazone 
• 1728-38-7 methyl enol ether of 2-methylcyclohexanone 
• 583-60-8 2-Methylcyclohexanone 
• 126171-31-1 6ξ-methyl-6-<2'-(2'',4'',4''-trimethyl-1'',3''dioxolan-2''-yl)ethyl>cyclohex-3-en-1-one 
• 4071-76-5 2-Methyl-6-(3-chloro-2-butenyl)cyclohexanone 
• 127996-73-0 2-(trans-but-2-enyl)-2-methylcyclohexanone 
• 4071-75-4 2-Methyl-2-(3-chloro-2-butenyl)cyclohexanone 
• 52815-01-7 2-Methyl-2-(3-trimethylsilyl-2-butenyl)-cyclohexanon 

Downstream Products

• 938-07-8 trans-10-methyldecal-2-one 

Relevant articles and documents

Formal (3+3) cycloaddition of silyl enol ethers catalyzed by trifric imide: Domino michael addition-claisen condensation accompanied with isomerization of silyl enol ethers

We describe here a Tf2NH-catalyzed formal (3+3) cycloaddition of silyl enol ethers with acrylates as a new domino reaction. In the domino sequence, the catalyst activates Michael addition, deprotonation of the resulting silyloxonium cation and

Lewis Acid Catalysed Michael-type Addition. A New Regio- and Diastereoselective Annulation Method using Methyl Vinyl Ketone

A new annulation method is presented, involving a boron trifluoride catalysed Michael addition of trialkylsilyl enol ethers to methyl vinyl ketone (MVK) in the presence of a hydroxylic compound.This methodology allows regiospecific 3-oxobutylation of eith

Organotin triflates as functional Lewis acids. A new entry to simple and efficient Robinson annulation

An efficient Robinson annulation has been established through the Michael addition of enol silyl ethers to α-enones catalyzed by dibutyltinbis(triflate) followed by the MeONa-mediated intramolecular aldol condensation of the adducts.