40737-07-3

Basic information

• Product Name: 2-bromo-6-methylphenanthridine 5-oxide
• Synonyms: 2-Bromo-6-methylphenanthridine-5-oxide
• CAS NO: 40737-07-3
• Molecular Formula: C₁₄H₁₀BrNO
• Molecular Weight: 288.1393
• Mol File: 40737-07-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 468.4°C at 760 mmHg
• Flash Point: 237.1°C
• Density: 1.49g/cm³
• Vapor Pressure: 1.69E-08mmHg at 25°C
• Refractive Index: 1.667
• CAS DataBase Reference: 2-bromo-6-methylphenanthridine 5-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-6-methylphenanthridine 5-oxide(40737-07-3)
• EPA Substance Registry System: 2-bromo-6-methylphenanthridine 5-oxide(40737-07-3)

Safety Data

• Hazardous Substances Data: 40737-07-3(Hazardous Substances Data)

Relevant articles and documents

Cathode Material Determines Product Selectivity for Electrochemical C?H Functionalization of Biaryl Ketoximes

The synthesis of polycyclic N-heteroaromatic compounds and their corresponding N-oxides has been developed through electrochemical C?H functionalization of biaryl ketoximes. The oxime substrates undergo dehydrogenative cyclization when a Pt cathode is used, resulting in unprecedented access to a wide range of N-heteroaromatic N-oxides. The products of the electrosynthesis are switched to the deoxygenated N-heteroaromatics by employing a Pb cathode through sequential anode-promoted dehydrogenative cyclization and cathodic cleavage of the N?O bond in the initially formed N-oxide.