40754-26-5Relevant articles and documents
Highly efficient reversible Z-E photoisomerization of a bridged azobenzene with visible light through resolved S1(nπ*) absorption bands
Siewertsen, Ron,Neumann, Hendrikje,Buchheim-Stehn, Bengt,Herges, Rainer,Naether, Christian,Renth, Falk,Temps, Friedrich
, p. 15594 - 15595 (2009)
(Graph Presented) The reversible Z-E photoswitching properties of the (Z) and (E) isomers of the severely constrained bridged azobenzene derivative 5,6-dihydrodibenzo[c,g][1,2]diazocine (1) were investigated quantitatively by UV/vis absorption spectroscop
Preparation method of azobenzene oxide derivative
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Paragraph 0022-0027, (2020/07/12)
The invention relates to a preparation method of an azobenzene oxide derivative. Nitrobenzene or a derivative thereof is used as a starting raw material, and is thoroughly reduced into the azobenzeneoxide derivative in an ethanol-water solution of an alka
Catalytic Selective Oxidative Coupling of Secondary N-Alkylanilines: An Approach to Azoxyarene
Ke, Lei,Zhu, Guirong,Qian, Hui,Xiang, Guangya,Chen, Qin,Chen, Zhilong
supporting information, p. 4008 - 4013 (2019/06/04)
Azoxyarenes are among important scaffolds in organic molecules. Direct oxidative coupling of primary anilines provides a concise fashion to construct them. However, whether these scaffolds can be prepared from secondary N-alkylanilines is not well explored. Here, we present a catalytic selective oxidative coupling of secondary N-alkylaniline to afford azoxyarene with tungsten catalyst under mild conditions. In addition, azoxy can be viewed as a bioisostere of alkene and amide. Several "azoxyarene analogues" of the corresponding bioactive alkenes and amides showed comparable promising anticancer activities.