40861-08-3

Basic information

• Product Name: N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE
• Synonyms: 1-CHLORO-4-([(4-CHLOROBENZYL)(HYDROXY)AMINO]METHYL)BENZENE;N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE;N,N-BIS(4-CHLOROBENZYL)HYDROXYLAMINE
• CAS NO: 40861-08-3
• Molecular Formula: C₁₄H₁₃Cl₂NO
• Molecular Weight: 282.17
• Mol File: 40861-08-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 434.1 °C at 760 mmHg
• Flash Point: 216.4 °C
• Appearance: /
• Density: 1.333g/cm³
• Vapor Pressure: 2.63E-08mmHg at 25°C
• Refractive Index: 1.63
• CAS DataBase Reference: N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE(40861-08-3)
• EPA Substance Registry System: N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE(40861-08-3)

Safety Data

• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot
• Hazardous Substances Data: 40861-08-3(Hazardous Substances Data)

Usage

General Description

N,N-Di(4-chlorobenzyl)hydroxylamine is a chemical compound that is used in the pharmaceutical and agricultural industries as a reagent and intermediate for the synthesis of various products. It is a water-soluble, crystalline solid that is stable under normal conditions. N,N-DI(4-CHLOROBENZYL)HYDROXYLAMINE has the ability to form bonds with organic compounds, making it useful in the preparation of diverse chemical compounds. Additionally, N,N-Di(4-chlorobenzyl)hydroxylamine has been found to exhibit antioxidant and anti-inflammatory properties, making it potentially useful for medical and cosmetic applications. However, it is important to handle this compound with care, as it can be harmful if ingested or inhaled, and can cause irritation to the skin and eyes.

InChI:InChI=1/C14H13Cl2NO/c15-13-5-1-11(2-6-13)9-17(18)10-12-3-7-14(16)8-4-12/h1-8,18H,9-10H2

Upstream product

• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 104-86-9 4-chlorobenzylamine 
• 1226954-85-3 10-methylacridinyl radical 

Downstream Products

• 711014-90-3 N-(4-chlorophenyl)methyl-N-(4-chlorophenyl)methyleneamine N-oxide 
• 851474-64-1 trans-[PtCl₄(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)2] 
• 926895-71-8 cis-[Re(IV)Cl₄(NH=C(Me)ON(p-CH₂C₆H₄Cl)2)2] 
• 851474-52-7 trans-[PtCl₂(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)2] 
• 851514-47-1 cis-[PtCl₂(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)2] 
• 253786-81-1 O-(1-naphthoyl)-N,N-bis(p-chlorobenzyl)hydroxylamine 
• 851474-60-7 [Ph₃PCH₂Ph][PtCl₃(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)] 
• 851474-72-1 [Ph₃PCH₂Ph][PtCl₅(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)] 

Relevant articles and documents

Graphene oxide as a metal-free catalyst for oxidation of primary amines to nitriles by hypochlorite

Graphene oxide catalyzes oxidation by NaClO of primary benzyl and aliphatic amines to a product distribution comprising nitriles and imines. Nitriles are the sole product for long chain aliphatic amines. Spectroscopic characterization suggests that percarboxylic and perlactone groups could be the active sites of the process.

Mechanism of the 10-methylacridinium ion-sensitized photooxidation of N,N-dibenzylhydroxylamine and its derivatives in acetonitrile

The 10-methylacridinium ion (MA+)-sensitized photooxidation of substituted N,N-dibenzylhydroxylamines (1) in acetonitrile occurred mainly by a superoxide ion mechanism to give N-benzylidenebenzylamine N-oxides (2) and hydrogen peroxide quantitatively. Analysis of substituent effects on the limiting quantum yield for formation of 2 showed that back electron transfer (ET) from the 10-methylacridinyl radical (MA.) to the radical cation 1+. proceeds in the Marcus 'normal region'. In addition, this back ET was found to take place in preference to one-electron reduction of O2 by MA..