40940-58-7

Basic information

• Product Name: allyl menthyl ether
• CAS NO: 40940-58-7
• Molecular Weight: 196.333
• Mol File: 40940-58-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: allyl menthyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: allyl menthyl ether(40940-58-7)
• EPA Substance Registry System: allyl menthyl ether(40940-58-7)

Safety Data

• Hazardous Substances Data: 40940-58-7(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 106-95-6 allyl bromide 
• 556-56-9 allyl iodid 
• 101-37-1 triallyl cyanurate 
• 15356-70-4 menthol 
• 136375-73-0 [[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]benzene 
• 753488-83-4 (1S,2R,4R)-2-(2,3-dimethylbut-2-en-1-yloxy)-1-isopropyl-4-methylcyclohexane 
• 195863-85-5 (1S,2R,4R)-1-isopropyl-4-methyl-2-(2-methylprop-2-en-1-yloxy)cyclohexane 
• 180477-54-7 (1S,2R,4R)-1-isopropyl-4-methyl-2-(3-methylbut-2-en-1-yloxy)cyclohexane 
• 27303-99-7 sodium menthoxide 

Downstream Products

• 76993-59-4 (-)-(1'R,2'S,5'R)-1-(2'-isopropyl-5'-methylcyclohexyloxy)acetaldehyde 
• 15356-70-4 menthol 
• 19876-19-8 Menthoxypropyl-methyl-dichlor-silan 
• 19876-26-7 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 
• 19876-20-1 Chloro-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 
• 20054-84-6 Menthoxypropyl-ethyl-dichlor-silan 
• 19876-24-5 Diethoxy-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-methyl-silane 
• 19876-21-2 Dichloro-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-phenyl-silane 
• 19876-22-3 Menthoxypropyl-trichlor-silan 
• 2216-51-5 (-)-menthol 
• 107941-60-6 (1S,2R,4R)-1-isopropyl-4-methyl-2-((Z)-prop-1-en-1-yloxy)cyclohexane 
• 491-07-6 (+/-)-menthone 
• 76993-60-7 (4aS,7aS,11aR,11bR)-6-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxymethyl)-dodecahydro-5,7-dioxa-dibenzo[a,c]cycloheptene 
• 19876-23-4 Ethoxy-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 

Relevant articles and documents

Nickel Hydride Catalyzed Cleavage of Allyl Ethers Induced by Isomerization

This report discloses the deallylation of O - and N -allyl functional groups by using a combination of a Ni-H precatalyst and excess Bronsted acid. Key steps are the isomerization of the O - or N -allyl group through Ni-catalyzed double-bond migration followed by Bronsted acid induced O/N-C bond hydrolysis. A variety of functional groups are tolerated in this protocol, highlighting its synthetic value.

Study of O-allylation using triazine-based reagents

Acid-catalyzed allylating reagent 2,4,6-tris(allyloxy)-1,3,5-triazine (TriAT-allyl) and its substituted derivatives have been developed. The reaction of acid-, and alkali-labile alcohols with these reagents in the presence of a catalytic amount of trifluoromethanesulfonic acid (TfOH) afforded the corresponding allyl ethers in good yields. Reactions using these reagents with an unsymmetrically-substituted regioisometric allyl group suggested that a single isometric allylic cation species would be involved.

The synthesis of a menthol derivative of 2-aminopurine as a fluorescent DNA lesion

An efficient synthetic route to the phosphoramidite of a menthol functionalized guanosine analog is presented. Two procedures were executed for the key introduction of the 6′-allyl menthyl moiety. Stille vinylation on 6-O-tosylguanosine followed by cross-