40943-24-6Relevant articles and documents
Copolymerization of Carbon Dioxide and Propylene Oxide by Binary Cobalt Salen Complexes with Various Anion Groups
Qin, Xiaoju,Du, LongChao,Wang, Cong,Yang, Zhao,Zhang, Min
, p. 547 - 556 (2017)
A series of salen–Co(III)(X) complexes tethering quaternary ammonium salts are designed to investigate the influence of the axial group X in the complex and the anion Y of quaternary ammonium salt on the copolymerization of CO2 and PO. By copolymerization, the complex 9, where X and Y are both 2,4-dinitrophenolate, has the highest catalytic efficiency. When X is OAc and Y is BF4 ?/NO3 ?, the complexes 11/12 have lower catalytic efficiency. For the complex 10, where X and Y are both OAc, the catalytic efficiency is the lowest. At the same time, complex 9 can produce the copolymer with the highest carbonate fraction and Mn. And the best copolymerization conditions were as follows: reaction temperature 30°C, copolymerization time 24 h, and CO2 pressure 2 MPa with complex 9. The thermal properties of the copolymers are also studied by differential scanning calorimetry (DSC) and thermogravimetry (TG).