40961-11-3

Basic information

• Product Name: 3-METHYL-2-PHENYLAMINO-BENZOIC ACID
• Synonyms: 3-METHYL-2-PHENYLAMINO-BENZOIC ACID
• CAS NO: 40961-11-3
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.25852
• Mol File: 40961-11-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-METHYL-2-PHENYLAMINO-BENZOIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHYL-2-PHENYLAMINO-BENZOIC ACID(40961-11-3)
• EPA Substance Registry System: 3-METHYL-2-PHENYLAMINO-BENZOIC ACID(40961-11-3)

Safety Data

• Hazardous Substances Data: 40961-11-3(Hazardous Substances Data)

Upstream product

• 108078-14-4 2-iodo-3-methylbenzoic acid 
• 62-53-3 aniline 
• 53663-39-1 3-methyl-2-bromobenzoic acid 

Downstream Products

• 1428865-08-0 C₁₆H₁₇NO₂ 
• 1428865-21-7 C₁₅H₁₇NO 
• 1428865-33-1 C₁₅H₁₅NO 

Relevant articles and documents

Sc(OTf)3-catalyzed dehydrogenative cyclization for synthesis of N-methylacridones

A novel method has been developed for the synthesis of substituted N-methylacridones from 2-(N-methyl-N-phenylamino)benzaldehydes via dehydrogenative cyclization. This transformation involves two primary processes: the aldehyde first coordinates with Sc(OTf)3 and induces the aromatic electrophilic substitution (SEAr) reaction to form the active intermediate N-methyl-acridin-9-ol, which is then quickly oxidized in situ to afford the acridones. Furthermore, the procedure involved is both environmental friendly and atom efficient; H2O is the only byproduct in this reaction.