41387-66-0

Basic information

• Product Name: dimethyl(3-phenoxyphenyl)(phenyl)silane
• CAS NO: 41387-66-0
• Molecular Weight: 304.464
• Mol File: 41387-66-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl(3-phenoxyphenyl)(phenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl(3-phenoxyphenyl)(phenyl)silane(41387-66-0)
• EPA Substance Registry System: dimethyl(3-phenoxyphenyl)(phenyl)silane(41387-66-0)

Safety Data

• Hazardous Substances Data: 41387-66-0(Hazardous Substances Data)

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 330-84-7 4-fluorophenoxybenzene 

Relevant articles and documents

Silyldefluorination of Fluoroarenes by Concerted Nucleophilic Aromatic Substitution

The reaction of readily generated silyl lithium reagents with various aryl fluorides to provide the corresponding aryl silanes is reported. DFT calculations reveal that the nucleophilic aromatic substitution of the fluoride anion by the silyl lithium reagent proceeds through concerted ipso substitution. In contrast to the classical nucleophilic aromatic substitution, this concerted ionic silyldefluorination also occurs on more electron-rich aryl fluorides.