41736-95-2Relevant articles and documents
Induced circular dichroism and UV-VIS absorption spectroscopy of cyclodextrin inclusion complexes: Structural elucidation of supramolecular azi-adamantane
Krois, Daniel,Brinker, Udo H.
, p. 11627 - 11632 (2007/10/03)
The first induced circular dichroism (ICD) analyses of diazirineγyciodextrin inclusion complexes are reported. The stoichiometries and association constants of the guestηost complexes with α-, β-, and γ- cyclodextrin were determined. In addition, with the α-cyclodextrin complex, UV-vis spectroscopy of water-ethanol solutions showed remarkable fine structure, probably indicating that the diazirine experiences a nonpolar microenvironment. These analytical methods provide details about the architecture and nature of these supramolecular carbene precursors.