4206-75-1

Basic information

• Product Name: CHLOROPHENYLSILANE 97
• Synonyms: CHLOROPHENYLSILANE 97;chlorophenyl-silan;Phenylchlorosilane;Phenol chlorosilane;Benzene, (chlorosilyl)-;Einecs 224-124-1;Silane, chlorophenyl-
• CAS NO: 4206-75-1
• Molecular Formula: C₆H₇ClSi
• Molecular Weight: 142.66
• EINECS: 224-124-1
• Product Categories: Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based
• Mol File: 4206-75-1.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 41 °C9 mm Hg(lit.)
• Flash Point: 129 °F
• Appearance: /
• Density: 1.070 g/mL at 25 °C(lit.)
• Vapor Pressure: 2.45mmHg at 25°C
• Refractive Index: n20/D 1.5260(lit.)
• CAS DataBase Reference: CHLOROPHENYLSILANE 97(CAS DataBase Reference)
• NIST Chemistry Reference: CHLOROPHENYLSILANE 97(4206-75-1)
• EPA Substance Registry System: CHLOROPHENYLSILANE 97(4206-75-1)

Safety Data

• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 16-26-36/37/39-45
• RIDADR: UN 2920 8/PG 2
• WGK Germany: 1
• Hazardous Substances Data: 4206-75-1(Hazardous Substances Data)

Usage

General Description

CHLOROPHENYLSILANE 97 is a chemical compound with the formula C6H5SiCl. It is a clear, colorless liquid with a boiling point of 210°C and is primarily used as an intermediate in the synthesis of other organosilicon compounds. It is commonly utilized as a reagent in organic chemistry reactions to introduce a phenylsilyl group into organic molecules. It is also used in the production of silicone resins and as a coupling agent in the production of certain polymers. CHLOROPHENYLSILANE 97 is known for its ability to efficiently functionalize organic compounds and is an important reagent in the field of synthetic organic chemistry.

InChI:InChI=1/C6H5ClSi/c7-8-6-4-2-1-3-5-6/h1-5H

Upstream product

• 694-53-1 phenylsilane 
• 98-13-5 Phenyltrichlorosilane 
• 80-10-4 diphenylsilyl dichloride 
• 108-90-7 chlorobenzene 
• 1070-78-6 1,1,1,3-tetrachloropropane 
• 775-12-2 diphenylsilane 

Downstream Products

• 76-86-8 Triphenylsilyl chloride 
• 80-10-4 diphenylsilyl dichloride 
• 3317-29-1 1.4-Bis-phenylsilyl-benzol 
• 20160-50-3 Monophenyl-pentafluorphenylsilan 
• 1009031-27-9 3-hexyl(phenyl)silane 
• 1144426-73-2 (E)-3,3-dimethyl-1-phenyl-1-phenylsilyl-1-butene 
• 18036-87-8 (cyclohexyl)phenylsilane 
• 21701-61-1 1-naphthylphenylsilane 
• 1221155-36-7 (2,6-dimethylphenyl)phenylsilane 
• 17932-93-3 (isopropoxy)phenylsilane 

Relevant articles and documents

Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: A potential system for facile preparation of hydrochlorosilanes

Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with LiBH4 as catalyst. A possible mechanism was proposed to explain the redistribution process.

Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane

Chlorosilanes are versatile reagents in organic synthesis and material science. A mild pathway is now reported for the quantitative conversion of hydrosilanes to silyl chlorides under visible-light irradiation using neutral eosin Y as a hydrogen-atom-transfer photocatalyst and dichloromethane as a chlorinating agent. Stepwise chlorination of di- and trihydrosilanes was achieved in a highly selective fashion assisted by continuous-flow micro-tubing reactors. The ability to access silyl radicals using photocatalytic Si?H activation promoted by eosin Y offers new perspectives for the synthesis of valuable silicon reagents in a convenient and green manner.

Hydrodehalogenation of alkyl halides catalyzed by a trichloroniobium complex with a redox active α-diimine ligand

A high-valent d0 niobium(v) complex, (α-diimine)NbCl3 (1), bearing a dianionic redox-active α-diimine ligand served as a catalyst for a hydrodehalogenation reaction of alkyl halides in the presence of PhSiH3. During the catalytic reaction, the redox-active α-diimine ligand allowed the complex to reversibly release and accept one-electron through switching its coordination mode between a dianionic folded form and a monoanionic planar one.