423158-70-7

Basic information

• Product Name: Trifluoro-methanesulfonic acid 2-[(2S,4aS,7R,8aR)-4,4,7-trimethyl-3-(3-methyl-but-2-enyl)-octahydro-benzo[e][1,3]oxazin-2-yl]-phenyl ester
• Synonyms: Trifluoro-methanesulfonic acid 2-[(2S,4aS,7R,8aR)-4,4,7-trimethyl-3-(3-methyl-but-2-enyl)-octahydro-benzo[e][1,3]oxazin-2-yl]-phenyl ester
• CAS NO: 423158-70-7
• Molecular Weight: 475.573
• Mol File: 423158-70-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trifluoro-methanesulfonic acid 2-[(2S,4aS,7R,8aR)-4,4,7-trimethyl-3-(3-methyl-but-2-enyl)-octahydro-benzo[e][1,3]oxazin-2-yl]-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoro-methanesulfonic acid 2-[(2S,4aS,7R,8aR)-4,4,7-trimethyl-3-(3-methyl-but-2-enyl)-octahydro-benzo[e][1,3]oxazin-2-yl]-phenyl ester(423158-70-7)
• EPA Substance Registry System: Trifluoro-methanesulfonic acid 2-[(2S,4aS,7R,8aR)-4,4,7-trimethyl-3-(3-methyl-but-2-enyl)-octahydro-benzo[e][1,3]oxazin-2-yl]-phenyl ester(423158-70-7)

Safety Data

• Hazardous Substances Data: 423158-70-7(Hazardous Substances Data)

Upstream product

• 84761-77-3 2-formylphenyl triflate 
• 55179-51-6 (-)-aminomenthol 
• 870-63-3 prenyl bromide 
• 423158-65-0 Trifluoro-methanesulfonic acid 2-((2S,4aS,7R,8aR)-4,4,7-trimethyl-octahydro-benzo[e][1,3]oxazin-2-yl)-phenyl ester 

Relevant articles and documents

Unexpected rearrangement in the Heck cyclization of positional isomers of chiral 2,3-disubstituted perhydro-1,3-benzoxazines

The intramolecular Heck cyclization on 2,3-disubstituted perhydro-1,3-benzoxazines, derived from (-)-8-amino menthol, easily proceeds at reflux of acetonitrile or DMF. The behavior of positional isomers was quite different. Reaction of 2-aryl-3-allyl perh