42577-03-7

Basic information

• Product Name: N-cyclohexylnonanamide
• Synonyms: N-cyclohexylnonanamide
• CAS NO: 42577-03-7
• Molecular Weight: 239.401
• Mol File: 42577-03-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-cyclohexylnonanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-cyclohexylnonanamide(42577-03-7)
• EPA Substance Registry System: N-cyclohexylnonanamide(42577-03-7)

Safety Data

• Hazardous Substances Data: 42577-03-7(Hazardous Substances Data)

Upstream product

• 108-91-8 cyclohexylamine 
• 143-08-8 nonyl alcohol 
• 111-66-0 oct-1-ene 
• 201230-82-2 carbon monoxide 
• 4998-76-9 cyclohexylamine hydrochloride 

Downstream Products

• 30249-29-7 N-nonylcyclohexanamine 

Relevant articles and documents

N-Formylation of amines by methanol activation

The homogeneous catalyzed dehydrogenation of methanol in a synthetically valuable cross-coupling reaction was achieved. By the use of a simple ruthenium-N-heterocyclic carbene complex, MeOH and primary or secondary amines can be converted into formamides.

Rh(I)-Catalyzed Hydroamidation of Olefins via Selective Activation of N-H Bonds in Aliphatic Amines

Hydroamidation of olefins constitutes an ideal, atom-efficient method to prepare carboxylic amides from easily available olefins, CO, and amines. So far, aliphatic amines are not suitable for these transformations. Here, we present a ligand- and additive-free Rh(I) catalyst as solution to this problem. Various amides are obtained in good yields and excellent regioselectivities. Notably, chemoselective amidation of aliphatic amines takes place in the presence of aromatic amines and alcohols. Mechanistic studies reveal the presence of Rh-acyl species as crucial intermediates for the selectivity and rate-limiting step in the proposed Rh(I)-catalytic cycle. (Chemical Formula Presented).