42590-97-6

Basic information

• Product Name: 2-METHOXY-THIOBENZAMIDE
• Synonyms: 2-METHOXY-THIOBENZAMIDE;Benzenecarbothioamide, 2-methoxy- (9CI);2-METHOXYBENZENECARBOTHIOAMIDE;2-Methoxybenzothioamide
• CAS NO: 42590-97-6
• Molecular Formula: C₈H₉NOS
• Molecular Weight: 167.23
• Product Categories: THIOAMIDE
• Mol File: 42590-97-6.mol
• Article Data: 12

Chemical Properties

• Melting Point: 110 -113°C
• Boiling Point: 299.4 °C at 760 mmHg
• Flash Point: 134.9 °C
• Appearance: /
• Density: 1.194 g/cm³
• Vapor Pressure: 0.0012mmHg at 25°C
• Refractive Index: 1.619
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2-METHOXY-THIOBENZAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHOXY-THIOBENZAMIDE(42590-97-6)
• EPA Substance Registry System: 2-METHOXY-THIOBENZAMIDE(42590-97-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38-43-36
• Safety Statements: 26-36/37/39-36/37
• Hazardous Substances Data: 42590-97-6(Hazardous Substances Data)

Usage

General Description

2-Methoxy-Thiobenzamide, also known as 2-Methoxybenzene-1-carbothioamide, is a chemical compound with the molecular formula C8H9NOS. It is classified as an amide and a thioamide, both types of organic compounds, with unique physical and chemical properties. It is used in the synthesis of other chemical compounds. This substance has a molar mass of 167.23 g/mol. The chemical properties of this compound, including its detailed reactivity, potential health hazards, environmental impact, and safe handling instructions, are typically provided in material safety data sheets by the supplier.

InChI:InChI=1/C8H9NOS/c1-10-7-5-3-2-4-6(7)8(9)11/h2-5H,1H3,(H2,9,11)

Upstream product

• 6609-56-9 2-methoxy-benzonitrile 
• 2439-77-2 2-methoxybenzamide 
• 333-20-0 potassium thioacyanate 
• 100-66-3 methoxybenzene 

Downstream Products

• 1258067-32-1 3,5-bis(2-methoxyphenyl)-1,2,4-thiadiazole 
• 1237051-62-5 4-(2,5-dichlorothien-3-yl)-2-(2-methoxyphenyl)-1,3-thiazole 
• 6609-56-9 2-methoxy-benzonitrile 
• 1028-96-2 2-(2-methoxyphenyl)quinazolin-4(3H)-one 
• 115299-16-6 ethyl 2-(2-methoxyphenyl)thiazole-4-carboxylate 
• 95211-55-5 3-[5-Ethoxycarbonylmethyl-2-(2-methoxy-phenyl)-thiazol-4-yl]-propionic acid ethyl ester 
• 23821-97-8 [2-(2-methoxy-phenyl)-4-phenyl-thiazol-5-yl]-acetic acid 

Relevant articles and documents

A multifunctional photoswitch: 6π electrocyclization versus esipt and metalation

A terthiazole-based molecular switch associating 6π electrocyclization, excited state intramolecular proton transfer (ESIPT), and strong metal binding capability was prepared. The photochemical and photophysical properties of this molecule and of the corr

Mo (CO)6-assisted Pd-supported magnetic graphene oxide-catalyzed carbonylation-cyclization as an efficient way for the synthesis of 4(3H)-quinazolinones

In this paper, a novel catalyst is introduced based on the immobilization of palladium on modified magnetic graphene oxide nanoparticles. The catalyst is characterized by several methods, including transmission electron microscopy, scanning electron microscopy, X-ray fluorescence, vibrating-sample magnetometer, Fourier transform-infrared and dynamic light scattering (DLS) analysis. The activity of the catalyst was investigated in the synthesis of 4(3H)-quinazolinones via Pd-catalyzed carbonylation-cyclization of N-(2-bromoaryl) benzimidamides by Mo (CO)6. The Mo (CO)6 is used as a carbon monoxide source for performing the reaction under mild conditions. The catalyst showed good reusability, and no change in activity was observed after 10?cycles of recovery.

A efficient protocol for the synthesis of thioamides in [DBUH][OAc] at room temperature

A novel, simple and eco-friendly method to synthesize thioamides from aryl nitriles and sodium sulfide (Na2S·9H2O) catalyzed by 1,8-diazabicyclo[5,4,0]undec-7-enium acetate ([DBUH][OAc]) ionic liquid (IL) at room temperature was developed in this paper. In this reaction, readily available inorganic salt (Na2S·9H2O) serves as the sulfur source, and various functional groups of aryl nitriles were well tolerated at room temperature. In addition, the products were easily separated from the IL which could be reused at least five times without considerable loss of its activity and applied in the green, concise synthesis of ethionamide.