42729-95-3Relevant articles and documents
Application of Cp2TiCl-Promoted Radical-Induced Cyclization: An Expeditious Access to [ a]-Annelated Indoles
Khan, Hina P. A.,Chakraborty, Tushar Kanti
, p. 8000 - 8012 (2020)
An efficient and novel route for assembling pyrrolo/piperido[1,2-a]indoles is portrayed involving a radical-mediated reductive epoxide opening reaction of N-tethered epoxy-indoles that trigger facile intramolecular cyclization followed by an oxidative quenching step. Capitalizing on the operational simplicity of the method involving just two steps and use of an efficient C-C bond-forming reaction, this radical-based protocol enables the modular assembly of an important class of N-fused indole derivatives with versatile functional and structural diversity.
Enantiopure sulforaphane analogues with various substituents at the sulfinyl sulfur: Asymmetric synthesis and biological activities
Khiar, Noureddine,Werner, Sabine,Mallouk, Siham,Lieder, Franziska,Alcudia, Ana,Fernandez, Inmaculada
experimental part, p. 6002 - 6009 (2009/12/26)
(Chemical Equation Presented) A convergent and high-yielding approach for the asymmetric synthesis of sulforaphane 2 and four analogues differently substituted at the sulfinyl sulfur has been developed. The key step of the synthesis is the diastereoselect
