4276-88-4

Basic information

• Product Name: [2,4,6-tris(1-methylethyl)phenyl]methanol
• Synonyms: [2,4,6-tris(1-methylethyl)phenyl]methanol
• CAS NO: 4276-88-4
• Molecular Weight: 234.382
• Mol File: 4276-88-4.mol
• Article Data: 10

Chemical Properties

• Melting Point: 83-84 °C
• Boiling Point: 160-170 °C(Press: 18 Torr)
• Density: 0.924±0.06 g/cm3(Predicted)
• CAS DataBase Reference: [2,4,6-tris(1-methylethyl)phenyl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: [2,4,6-tris(1-methylethyl)phenyl]methanol(4276-88-4)
• EPA Substance Registry System: [2,4,6-tris(1-methylethyl)phenyl]methanol(4276-88-4)

Safety Data

• Hazardous Substances Data: 4276-88-4(Hazardous Substances Data)

Usage

Description

[2,4,6-tris(1-methylethyl)phenyl]methanol, also known as Lowinox TBM6, is a chemical compound with the molecular formula C25H36O. It is a white crystalline solid that serves as an essential antioxidant in various industrial applications.

Uses

Used in Polymer and Plastics Industry:
[2,4,6-tris(1-methylethyl)phenyl]methanol is used as an antioxidant for stabilizing polymers and plastics. It prevents the degradation of these materials due to exposure to heat and oxygen, thereby preserving their quality and extending their longevity.
Used in Rubber Industry:
In the rubber industry, [2,4,6-tris(1-methylethyl)phenyl]methanol is used as a stabilizer to enhance the durability and performance of rubber products by protecting them from the damaging effects of heat and oxygen.
Used in Lubricants Industry:
[2,4,6-tris(1-methylethyl)phenyl]methanol is also utilized as a stabilizer in the lubricants industry, where it helps maintain the stability and efficiency of lubricants by counteracting the negative effects of heat and oxygen.

Upstream product

• 57199-00-5 2,4,6-triisopropylbenzoyl chloride 
• 7757-82-6 sodium sulfate 
• 63846-76-4 ethyl 2,4,6-tri-isopropylbenzoate 
• 50-00-0 formaldehyd 
• 21524-34-5 2,4,6-triisopropyl-1-bromobenzene 
• 4276-84-0 2,4,6-triisopropylbenzyl cyanide 
• 38580-86-8 2,4,6-triisopropylbenzyl chloride 
• 82797-36-2 isopropyl 2,4,6-triisopropylthiobenzoate 
• 717-74-8 1,3,5-triisopropyl benzene 
• 4276-85-1 2-(2,4,6-triisopropylphenyl)acetic acid 
• 82797-40-8 2'-methyl-2'-heptyl 2,4,6-triisopropylthiobenzoate 
• 49623-71-4 2,4,6-triisopropylbenzoic acid 
• 24249-82-9 2,4,6-triisopropylbenzaldehyde 

Downstream Products

• 166519-14-8 2-(bromomethyl)-1,3,5-triisopropylbenzene 
• 1002751-43-0 2,4,6-triisopropylbenzyl 2,5-diiodobenzoate 
• 1371586-31-0 2,4,6-tris(1-methylethyl)benzyl 2-methyl-3-oxo-3-phenylpropanoate 
• 1908442-13-6 3-(t-butyl)-4-(2,6-dimethoxyphenyl)-2-(2,4,6-triisopropylbenzyl)-2,3dihydrobenzo[d][1,3]oxaphosphole 
• 136667-09-9 α-(2,4,6-triisopropylphenyl)acetophenone-d2 
• 90432-29-4 1-phenyl-2-[2,4,6-tris(1-methylethyl)phenyl]ethanone 
• 24249-82-9 2,4,6-triisopropylbenzaldehyde 
• 1371586-30-9 2,4,6-tris(1-methylethyl)benzyl 2-methyl-3-oxobutanoate 
• 166518-60-1 avasimibe 
• 4276-84-0 2,4,6-triisopropylbenzyl cyanide 
• 4276-85-1 2-(2,4,6-triisopropylphenyl)acetic acid 
• 38580-86-8 2,4,6-triisopropylbenzyl chloride 
• 1308331-89-6 2,4,6-triisopropylbenzyl (2S)-2-(dimethylamino)propanoate 

Relevant articles and documents

Asymmetric Cross [10+2] Cycloadditions of 2-Alkylidene-1-indanones and Activated Alkenes under Phase-Transfer Catalysis

Isobenzofulvene species are versatile synthons in organic chemistry, which have been employed in diverse challenging higher-order cycloaddition reactions. Here, the first chemoselective and asymmetric cross [10+2] cycloaddition reaction between activated 2-alkylidene-1-indanones and a variety of electron-deficient alkenes has been developed, relying on the in situ generation of dearomative 1-hydroxyl isobenzofulvene anion intermediates under the catalysis of a newly designed bulky cinchona-derived phase-transfer compound. An array of fused frameworks with multifunctionalities were generally furnished in excellent diastereo- and enantioselectivity, even at 1 mol % catalyst loadings.

Substrate range of the titanium TADDOLate catalyzed asymmetric fluorination of activated carbonyl compounds

The substrate range of the [TiCl2(TADDOLate)] (TADDOL=α,α,α′,α′-tetraaryl-1,3-dioxolane-4, 5-dimethanol)-catalyzed asymmetric α-fluorination of activated β-carbonyl compounds has been investigated. Optimal conditions for catalysis are characterized by using 5 mol-% of TiCl2(naphthalen-1- yl)-TADDOLate) as catalyst in a saturated (0.14 mol/l) MeCN solution of F-TEDA (1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis- [tetrafluoroborate]) at room temperature. A series of α-methylated β-keto esters (3-oxobutanoates, 3-oxopentanoates) with bulky benzyl ester groups (60-90% ee) or phenyl ester (67-88% ee) have been fluorinated readily, whereas α-acyl lactones were also readily fluorinated, but gave lower inductions (13-46% ee). Double stereochemical differentiation in β-keto esters with chiral ester groups raised the stereoselectivity to a diastereomeric ratio (dr) of up to 96.5:3.5. For the first time, β-keto S-thioesters were asymmetrically fluorinated (62-91.5% ee) and chlorinated (83% ee). Lower inductions were observed in fluorinations of 1,3-diketones (up to 40% ee) and β-keto amides (up to 59% ee). General strategies for preparing activated β-carbonyl compounds as important model substrates for asymmetric catalytic α-functionalizations are presented (>60 examples). Copyright

Chemosensory performance of molecularly imprinted fluorescent conjugated polymer materials

Fluorescent conjugated polymers are an attractive basis for the design of low detection limit sensing devices owing to their intrinsic signal amplification capability. A simple and universal method to rationally control or fine-tune the chemodetection sel