4282-44-4

Basic information

• Product Name: 1-IODOUNDECANE
• Synonyms: 1-iodo-undecan;Undecane, 1-iodo-;N-UNDECYL IODIDE;1-IODOUNDECANE;1-Iodoundecane,98%;1-IODOUNDECANE, STABILIZED WITH COPPER;1-Iodoundecane,99%;##DISCONTINUED## 1-Iodoundecane, 98%
• CAS NO: 4282-44-4
• Molecular Formula: C₁₁H₂₃I
• Molecular Weight: 282.2
• Product Categories: Iodine Compounds;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks;Aliphatics
• Mol File: 4282-44-4.mol
• Article Data: 10

Chemical Properties

• Melting Point: 2°C
• Boiling Point: 125-130 °C5 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: clear colourless liquid
• Density: 1.22 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00589mmHg at 25°C
• Refractive Index: n20/D 1.4849(lit.)
• Sensitive: Light Sensitive
• BRN: 1735991
• CAS DataBase Reference: 1-IODOUNDECANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-IODOUNDECANE(4282-44-4)
• EPA Substance Registry System: 1-IODOUNDECANE(4282-44-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 4282-44-4(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

1-Iodoundecane (cas# 4282-44-4) is a compound useful in organic synthesis.

Synthesis Reference(s)

Tetrahedron Letters, 9, p. 5787, 1968 DOI: 10.1016/S0040-4039(00)76351-9

General Description

1-Iodoundecane is one of the volatile constituent of urine of a normal male mice. The reaction of 1-iodoundecane with fluoride sources has been investigated.

InChI:InChI=1/C11H23I/c1-2-3-4-5-6-7-8-9-10-11-12/h2-11H2,1H3

Upstream product

• 81609-28-1 Undecyltellanyl-benzene 
• 56-23-5 tetrachloromethane 
• 71-43-2 benzene 
• 112-54-9 Dodecanal 
• 821-95-4 1-undecene 
• 1731-86-8 methyl undecanoate 
• 629-27-6 1-Iodooctane 
• 627-90-7 ethyl undecanoate 
• 78371-02-5 C₃₀H₃₈O 
• 78371-01-4 1-ethoxyundecane 
• 14620-52-1 1,1-dimethoxy-dodecane 
• 222190-76-3 2,3-dimethyl-2-(1-methoxydodecyl)peroxybut-3-ene 
• 88008-61-1 C₁₅H₃₃MgN 
• 83486-09-3 C₁₇H₂₈I₂Te 

Downstream Products

• 41240-52-2 diethyl 2-undecylmalonate 
• 1120-21-4 n-Undecane 
• 103539-05-5 3-undecylcyclohexan-1-one 
• 629-63-0 myristonitrile 
• 1120-36-1 1-tetradecene 
• 506-05-8 1-fluoroundecane 
• 821-95-4 1-undecene 
• 58898-10-5 1-(Dodecane-1-sulfinyl)-1-methylsulfanyl-cyclohexane 
• 629-97-0 n-docosane 
• 59812-96-3 (R)-5-hexadecanolide 
• 92791-77-0 2-n-undecylthiophene 
• 112-42-5 undecyl alcohol 
• 116262-03-4 (R)-2-n-undecanylcyclopentanone 

Relevant articles and documents

Homogeneous catalysis, heterogeneous recycling: A new family of branched molecules with hydrocarbon or fluorocarbon chains for the Friedl?nder synthesis of quinoline under solvent-free conditions

A new family of branched catalysts with hydrocarbon or fluorocarbon chains was used to catalyze Friedl?nder reaction between 2-aminoarylketones and α-methylene ketones under solvent-free conditions in good to excellent yields. The catalysts exhibit temperature-dependent solubility and such a thermomorphic character allows them to be recovered by filtration conveniently at room temperature and reused at least five times. To some extent, the branched catalysts with hydrocarbon chains are superior to those with fluorocarbon chains, as they are cheaper and more biodegradable.

Intramolecular homolytic displacements. 30. Functional decarbonylative transformations of aldehydes via homolytically induced decomposition of unsaturated peroxyacetals

Homolytically induced decompositions of unsaturated peroxyacetals, synthesized from aldehydes, gave alkoxyalkoxyl radicals that yielded alkyl radicals by rapid β-scission. The latter radicals could react with several types of "transfer agents" to smoothly bring about homolytic decarbonylative functional group transformations of aldehydes into halides, hydrocarbons, xanthates, alkanenitriles, 2-alkyl-3-chloromaleic anhydrides, 1-phenylalk-1-ynes, and ethyl 2-alkylpropenoates.