42858-33-3

Basic information

• Product Name: 1-Propanone, 1-phenyl-2-(phenylseleno)-
• CAS NO: 42858-33-3
• Molecular Formula: C15H14OSe
• Molecular Weight: 289.236
• Mol File: 42858-33-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 1-phenyl-2-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1-phenyl-2-(phenylseleno)-(42858-33-3)
• EPA Substance Registry System: 1-Propanone, 1-phenyl-2-(phenylseleno)-(42858-33-3)

Safety Data

• Hazardous Substances Data: 42858-33-3(Hazardous Substances Data)

Upstream product

• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 
• 34837-55-3 Phenylselenyl bromide 
• 42572-42-9 phenylselenium trichloride 
• 104755-22-8 C₁₅H₁₄Cl₂OSe 
• 5707-04-0 Phenylselenyl chloride 
• 93-55-0 1-phenyl-propan-1-one 
• 873-66-5 1-propenylbenzene 
• 1666-13-3 diphenyl diselenide 
• 645-96-5 Benzeneselenol 

Downstream Products

• 1194360-66-1 C₁₈H₁₈O₂Se 
• 84993-33-9 C₁₆H₁₆Se 
• 831200-81-8 phenyl-N-(1-phenyl-2-(phenylselanyl)propylidene)methanamine 
• 93-54-9 1-Phenyl-1-propanol 
• 768-03-6 Phenyl vinyl ketone 
• 116333-32-5 erythro-1-Phenyl-2-(phenylseleno)propan-1-ol 
• 116333-32-5 threo-1-Phenyl-2-(phenylseleno)propan-1-ol 
• 56253-60-2 trimethyl-phenylselanylmethyl-silane 
• 1218948-27-6 C₁₈H₁₉NSe 

Relevant articles and documents

Visible-light-induced oxidative coupling of vinylarenes with diselenides leading to α-aryl and α-alkyl selenomethyl ketones

A visible-light-induced oxidative coupling of diselenides with readily available vinylarenes is demonstrated. This benign protocol allows one to access a wide range of α-aryl and α-alkyl selenomethyl ketones in good yields with excellent functional group compatibility. The distinct advantages of this protocol over all previous methods include the use of a green solvent and air as an oxidant and the lack of a photocatalyst, a base, and an oxidant as well as better green chemistry matrices. Furthermore, the title reaction can be performed with natural sunlight, the most sustainable energy source imaginable. Additionally, the mild reaction conditions, easy operation and suitability for the modification of styrene-functionalized biomolecules make the current reaction system a more attractive method for the synthesis of a variety of medicinal and agrochemical compounds of interest.

A radical cyclization route to cyclic imines

A novel route to cyclic imines based on 5-exo radical cyclization is explored. The radical precursors are imines prepared from allylamine and readily available α-phenylselenenyl ketones.

Use of phenylselenium trichloride for simple and rapid preparation of α-phenylselanyl aldehydes and ketones

α-Phenylselanyl aldehydes are prepared on a large scale by reaction of PhSeCl3 with the corresponding aldehydes in acetonitrile without isolation of the intermediate dichloro adducts. This method has been applied to α-phenylselanyl ketones deri