42926-91-0

Basic information

• Product Name: 1,6-Anhydro-3-O-benzyl-beta-L-idopyranose min. 98%
• Synonyms: 1,6-Anhydro-3-O-benzyl-beta-L-idopyranose min. 98%;1,6-Anhydro-3-O-(phenylmethyl)-beta-L-idopyranose;1,6-Anhydro-3-O-benzyl-beta-L-idopyranose;1,6-Anhydro-3-O-benzyl-b-L-idopyranose
• CAS NO: 42926-91-0
• Molecular Formula: C₁₃H₁₆O₅
• Molecular Weight: 252.26
• Mol File: 42926-91-0.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,6-Anhydro-3-O-benzyl-beta-L-idopyranose min. 98%(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Anhydro-3-O-benzyl-beta-L-idopyranose min. 98%(42926-91-0)
• EPA Substance Registry System: 1,6-Anhydro-3-O-benzyl-beta-L-idopyranose min. 98%(42926-91-0)

Safety Data

• Hazardous Substances Data: 42926-91-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 334834-37-6 1,6-anhydro-2,3,4-triO-trimethylsilyl-β-L-idopyranose 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 5531-09-9 3-O-benzyl-L-idopyranose 
• 37776-17-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-β-L-idofuranose 
• 37776-15-1 6-O-Benzoyl-3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 60619-47-8 1,6-anhydro-β-L-idopyranose 
• 87357-54-8 6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose 
• 81562-09-6 6-hydroxy-1,2:3,5-di-O-isopropylidene-α-D-glucofuranoside 
• 882689-03-4 Benzoic acid (S)-2-((3aR,5S,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-methanesulfonyloxy-ethyl ester 

Downstream Products

• 334834-19-4 1,6-anhydro-2-O-benzoyl-3-O-benzyl-β-L-idopyranoside 
• 676342-84-0 Trifluoro-methanesulfonic acid (1S,2R,3S,4R,5S)-3-benzyloxy-2-trifluoromethanesulfonyloxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl ester 
• 676342-80-6 methyl 4-O-(2-azido-4-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-α-L-idopyranosiduronic acid 
• 676342-81-7 methyl 4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-sulfonato-α-D-glucopyranosyl)-3-O-benzyl-2-O-sulfonato-α-L-idopyranosiduronic acid 
• 676342-75-9 1,6-anhydro-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-β-L-idopyranoside 
• 676342-79-3 methyl 4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-α-L-idopyranoside 
• 676342-88-4 (2R,3S,4S,5R,6R)-3-((2R,3R,4R,5S,6R)-3-Azido-4-benzoyloxy-6-benzoyloxymethyl-5-benzyloxy-tetrahydro-pyran-2-yloxy)-5-benzoyloxy-4-benzyloxy-6-methoxy-tetrahydro-pyran-2-carboxylic acid 
• 676342-78-2 methyl 6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-α-L-idopyranoside 
• 676342-76-0 6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate 
• 61237-60-3 2,4-di-O-acetyl-1,6-anhydro-3-O-benzyl-β-L-idopyranose 
• 1314746-21-8 1,6-anhydro-4-O-[2-azido-6-O-tert-butyldiphenylsilyl-2-deoxy-4-O-(2-naphthylmethyl)-α-D-glucopyranosyl]-3-O-benzyl-β-L-idopyranose 
• 657395-04-5 C₇₄H₇₂N₆O₁₈ 
• 657395-06-7 4-O-[2-azido-6-O-benzoyl-3-O-benzyl-2-deoxy-4-O-(2-naphthylmethyl)-α-D-glucopyranosyl]-2-O-benzoyl-3-O-benzyl-6-O-levulinyl-L-idopyranosyl levulinate 
• 657395-07-8 4-O-[2-azido-6-O-benzoyl-3-O-benzyl-2-deoxy-4-O-(2-naphth-ylmethyl)-α-D-glucopyranosyl]-2-O-benzoyl-3-O-benzyl-6-O-levulinyl-L-idopyranosyl trichloroacetimidate 

Relevant articles and documents

Method for synthesizing fondaparinux sodium monosaccharide intermediate

The invention discloses a method for synthesizing a fondaparinux sodium monosaccharide intermediate. According to the method, a fondaparinux sodium monosaccharide fragment intermediate, namely 1,6-dehydro-3-O-benzyl-beta-L-idopyranose, is prepared by taki

Synthesis of Fondaparinux: Modular synthesis investigation for heparin synthesis

The anti-thromboembolic pentasaccharide Fondaparinux was synthesized in 36 steps for the longest linear route, with 0.017% overall yield from d-glucose. Only three kinds of protecting groups were used for hydroxyl protection, Bn, Ac, and Bz, to accomplish this complex synthesis without decreasing the synthetic efficiency. Three l-idopyranosyl donors were investigated. Thioethyl glycoside is an efficient donor for l-idopyranosyl glycosylation with full α-selectivity, while l-idopyranosyl trichloroacetimidate resulted in poor α/β selectivity. A practical synthesis of key intermediate 1,6-anhydro-l-idopyranose 17 by H+/β-CD catalyst was developed.

An efficient synthesis of l-idose and l-iduronic acid thioglycosides and their use for the synthesis of heparin oligosaccharides

Efficient preparations of thioglycoside derivatives of l-idose and l-iduronic acid are described. The method avoids the tedious chromatographic separations of furanose and pyranose anomeric mixtures, and affords the thioglycosides in a stereoselective man