42967-76-0

Basic information

• Product Name: piperidinium 4-methylbenzenecarbodithiolate
• Synonyms: piperidinium 4-methylbenzenecarbodithiolate
• CAS NO: 42967-76-0
• Molecular Weight: 253.433
• Mol File: 42967-76-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: piperidinium 4-methylbenzenecarbodithiolate(CAS DataBase Reference)
• NIST Chemistry Reference: piperidinium 4-methylbenzenecarbodithiolate(42967-76-0)
• EPA Substance Registry System: piperidinium 4-methylbenzenecarbodithiolate(42967-76-0)

Safety Data

• Hazardous Substances Data: 42967-76-0(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 97270-47-8 4-(methyl)thiobenzoyl diphenylphosphino sulfide 
• 97346-90-2 bis[4-(methyl)thiobenzoyl] trisulfide 
• 97346-95-7 bis[4-(methyl)thiobenzoyl] tetrasulfide 
• 97270-50-3 tellurium bis<4-(methyl)dithiobenzoate> 
• 120449-42-5 Se-phenyl 4-methylbenzenecarboselenothioate 
• 53724-36-0 sodium 4-(methyl)dithiobenzoate 
• 64586-19-2 Acetic 4-methylthiobenzoic thioanhydride 
• 60410-77-7 bis(4-methylbenzenethiocarbonyl) sulphide 
• 2168-80-1 4-methyldithioic acid 
• 3335-25-9 4-methylthiobenzoyl chloride 

Downstream Products

• 342415-86-5 bis(4-methylthiobenzoylthio)phenylarsine 
• 85161-01-9 4-Methyl-dithiobenzoic acid (E)-styryl ester 
• 85170-56-5 2-(4-nitrophenyl)-vinyl p-toluenedithiocarboxylate 
• 32538-29-7 di(p-tolyl)tin dichloride 
• 922178-11-8 In(C₆H₄CH₃CS₂)3 
• 922178-09-4 Ga(C₆H₄CH₃CS₂)3 
• 84372-75-8 bis(diphenylantimony) sulfide 
• 895166-03-7 2,4-diphenyl-1,3,2,4-dithiadistibetane 
• 5925-77-9 S-methyl 4-methylbenzothioate 
• 5977-80-0 O-methyl 4-methylbenzenecarbothioate 
• 20849-31-4 4-Methyldithiobenzoesaeurephenylester 
• 2168-80-1 4-methyldithioic acid 
• 80047-73-0 (4-methylbenzoyl)(4-methylbenzenecarbothioyl) sulfide 

Relevant articles and documents

Se-Aryl Alkane- or Arenecarboselenothioates: Synthesis and Some Reactions

A series of Se-aryl carboselenothioates 3 (RCSSeAr, R=alkyl, aryl) were synthesized and characterized from the reaction of bis(thioacyl) sulfides 1 with sodium areneselenolates.The thionselenolesters 3 are stable (liquid or crystals) both thermally and to moisture.Reactions of 3 with aliphatic primary and secondary amines gave the corresponding ammonium carbodithioates 8 together with diphenyl diselenide 7.In contrast, treatment with aromatic amines or sodium alcoholates afforded the corresponding thioamides or O-alkyl or O-aryl thionoesters in good yields.The oxidation of 3 with m-chloroperbenzoic acid gave the corresponding sulfides 12 and acyl arylseleno sulfides 13 which are formed by a rearrangement of the ArSe group to the thiocarbonyl sulfur atom.

Preparation and Some Reactions of Selenium and Tellurium Bis(dithiocarboxylates)

A number of selenium- 2 and tellurium bis(dithiocarboxylates) 3 have been prepared by the reaction of piperidinium or sodium dithiocarboxylates 1 with sodium seleno- and telluropentathionates.The orange or red products are stable towards heat and moisture

Preparation and Some Reactions of Bis(thioacyl) Sulfides

Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.