4337-36-4

Basic information

• Product Name: 2-Cyclohexen-1-one,2,3-dihydroxy-
• CAS NO: 4337-36-4
• Molecular Weight: 128.128
• Mol File: 4337-36-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one,2,3-dihydroxy- (CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one,2,3-dihydroxy- (4337-36-4)
• EPA Substance Registry System: 2-Cyclohexen-1-one,2,3-dihydroxy- (4337-36-4)

Safety Data

• Hazardous Substances Data: 4337-36-4(Hazardous Substances Data)

Upstream product

• 19379-74-9 3-chloro-cyclohexane-1,2-dione 
• 87-66-1 2-hydroxyresorcinol 
• 897-78-9 2,6-bis(phenylmethylene)cyclohexanone 
• 822-87-7 2-Chlorocyclohexanone 
• 930-68-7 cyclohexenone 
• 6586-43-2 2,5-dibenzylidenecyclohexanol 

Downstream Products

• 105872-31-9 3-Hydroxy-2-methoxycyclohex-2-en-1-on 
• 2630-64-0 syn-cyclohexane-1,2,3-triol 
• 2630-65-1 rac-cyclohexane-1,2,3-triol 
• 5435-42-7 2-phenylhydrazono-adipic acid 
• 105872-29-5 3-anilino-2-hydroxy-cyclohex-2-enone 

Relevant articles and documents

Oxidation of α,β-unsaturated carbonyl groups with ruthenium (III)- chloride and peracetic acid: A new access to α-oxo-ene-diols

A one pot oxidation of cyclic unsaturated carbonyl and carboxylic compounds with ruthenium (III)-chloride and peracetic acid to the corresponding α-oxo-ene-diols (aci-reductones) has been developed.

Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate

Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper(I)-catalyzed acyloxylations of 1-methoxycyclohex-1-ene (1a) by means of tert-butyl peroxycarboxylates 2a, b.