436853-30-4

Basic information

• Product Name: 4,4'-BipyridiniuM, 1,1'-bis[(4-boronophenyl)Methyl]-, dibroMide
• Synonyms: 4,4'-BipyridiniuM, 1,1'-bis[(4-boronophenyl)Methyl]-, dibroMide;1,1'-Bis(4-boronobenzyl)-[4,4'-bipyridine]-1,1'-diium bromide;DTORDTSFDZJPJM-UHFFFAOYSA-L
• CAS NO: 436853-30-4
• Molecular Formula: C24H24B2Br2N2O4
• Molecular Weight: 585.88836
• Mol File: 436853-30-4.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4,4'-BipyridiniuM, 1,1'-bis[(4-boronophenyl)Methyl]-, dibroMide(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-BipyridiniuM, 1,1'-bis[(4-boronophenyl)Methyl]-, dibroMide(436853-30-4)
• EPA Substance Registry System: 4,4'-BipyridiniuM, 1,1'-bis[(4-boronophenyl)Methyl]-, dibroMide(436853-30-4)

Safety Data

• Hazardous Substances Data: 436853-30-4(Hazardous Substances Data)

Upstream product

• 553-26-4 4,4'-bipyridine 
• 143805-78-1 2-(4-bromomethyl-phenyl)-5,5-dimethyl-[1,3,2]dioxaborinane 
• 68162-47-0 4-bromomethylphenylboronic acid 

Relevant articles and documents

Photoinduced electron transfer quenching and sugar effects on the electrostatic interaction between an anionic Ru(II) complex and cationic bipyridinium derivatives functionalized with boronic acids

The photoinduced electron transfer quenching of an anionic ruthenium(II) metal-ligand-complex (Ru(dpp(SO3Na))2(mcbpy)Cl2 by two boronic acid functionalized benzyl viologen (BV2+) derivatives has been investigated as well as their response to sugar. The electrostatic interaction between these two charge species lead to the formation of static quenching which is removed in presence of sugar due to the formation of a neutral zwitterionic quencher. Spectral data, quenching parameters and sugar titration curves are presented and discussed in term of future developments of optical sensors for sugar.

Highly selective ensembles for D-fructose based on fluorescent method in aqueous solution

Three highly sensitive and selective switches for monosaccharides were composed by anionic polyelectrolyte PPPSO3Na and cationic viologen quencheres BBVs. The sensing processes of three ensembles (PPPSO 3Na/o-BBV, PPPSO3Na/m-BBV and PPPSO3Na/p-BBV) to common seven monosaccharides have been determined by fluorescence spectra at pH 7.4 buffer solution. The results show that the three sensing ensembles all embody higher selectivity and sensitivity for d-fructose with reversible "on-off-on" fluorescence response. The research results can provide a new mode for developing highly selective probes.