443-83-4Relevant articles and documents
Synthesis of aryl fluorides on a solid support and in solution by utilizing a fluorinated solvent
Doebele, Marion,Vanderheiden, Sylvia,Jung, Nicole,Braese, Stefan
supporting information; experimental part, p. 5986 - 5988 (2010/10/01)
(Figure Presented) F for fast: The perfluorinated solvent C 6F14 is the key to a new variant of the BalzSchiemann reaction for the synthesis of fluorinated arenes. Triazenes are converted into fluoroarenes under mild con-ditions on a support and in solution (see scheme). The method is straightforward and inexpensive, and yields previously difficult-to-prepare fluoroarenes in high purity.
Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: A versatile synthetic method
Aitken, R. Alan,Hodgson, Philip K. G.,Oyewale, Adebayo O.,Morrison, John J.
, p. 1163 - 1164 (2007/10/03)
Flash vacuum pyrolysis over magnesium at 600°C results in efficient dehalogenation of a variety of organic halides and provides a preparatively useful method for C-C bond formation and other reactions.