445027-76-9Relevant articles and documents
New insights into the reaction of t-butylhydroperoxide with dichloro- and dimethyl(dioxo)molybdenum(VI)
Groarke, Michelle,Gon?alves, Isabel S.,Herrmann, Wolfgang A.,Kühn, Fritz E.
, p. 108 - 112 (2002)
Lewis-base adducts of dichlorodioxomolybdenum(VI) and dimethyldioxomolybdenum(VI) react in an equilibrium reaction with excess t-butylhydroperoxide (TBHP) under the formation of a seven-coordinated molybdenum(VI) complexes displaying a η1-alkyl
Amphiphilic polypyridyl ruthenium complexes: Synthesis, characterization and aggregation studies
Bhand, Sujit,Lande, Dipali N.,Pereira, Eulália,Gejji, Shridhar P.,Weyhermüller, Thomas,Chakravarty, Debamitra,Puranik, Vedavati G.,Salunke-Gawali, Sunita
, p. 96 - 107 (2019/03/13)
Synthesis and characterization of five amphiphilic ruthenium(II) complexes of the type [Ru(Cn)3].(PF6)2 (Cn = 4,4′-dialkyl-2,2′-bipyridine, n = 5(4,4′-dipentyl), 6(4,4′-dihexyl), 7(4,4′-diheptyl), 8(4,4′-dioctyl), 9(4,4′-dinonyl)) have been investigated. Single crystal X-ray structures of 4,4′-dipentyl-2,2′-bipyridine (C5), 4,4′-dioctyl-2,2′-bipyridine (C8) ligands and [Ru(C5)3](PF6)2 complex are elucidated. Structural inferences are corroborated through the density functional theory. Molecular aggregations in these systems in aqueous and non-aqueous media have further been analyzed from FESEM experiments.