447405-46-1

Basic information

• Product Name: cis-bromo[1,2-bis(dicyclohexylphosphino)ethane][2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]nickel(II)
• Synonyms: cis-bromo[1,2-bis(dicyclohexylphosphino)ethane][2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]nickel(II)
• CAS NO: 447405-46-1
• Molecular Weight: 764.277
• Mol File: 447405-46-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-bromo[1,2-bis(dicyclohexylphosphino)ethane][2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-bromo[1,2-bis(dicyclohexylphosphino)ethane][2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]nickel(II)(447405-46-1)
• EPA Substance Registry System: cis-bromo[1,2-bis(dicyclohexylphosphino)ethane][2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]nickel(II)(447405-46-1)

Safety Data

• Hazardous Substances Data: 447405-46-1(Hazardous Substances Data)

Upstream product

• 447405-43-8 [NiBr(o-C₆H₄B(pinacolate))(PPh₃)2] 
• 23743-26-2 1,2-bis-(dicyclohexylphosphino)ethane 
• 1437769-72-6 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl trifluoromethanesulfonate 
• 447405-44-9 trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II) 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 269410-06-2 2-(2-bromophenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 244205-40-1 (2-bromophenyl)boronic acid 

Downstream Products

• 114907-51-6 [η²-benzyne][1,2-bis(dicyclohexylphosphino)ethane]nickel(0) 
• 473829-82-2 [NiBr(C₆H₅)(1,2-bis(dicyclohexylphosphino)ethane)] 

Relevant articles and documents

Preparation of Aryne-Nickel Complexes from ortho-Borylaryl Triflates

A facile method for preparing diverse aryne-nickel complexes from readily synthesized ortho-borylaryl triflates is described. Exploratory synthetic applications, including the synthesis of 1,2-difunctionalized arenes, based on the nucleophilic character of the aryne-nickel complexes are also demonstrated.