45791-94-4Relevant articles and documents
Variation of Counterion Binding in Micelles of Cetyltrimethylammonium Hydroxide
Chalmovich, Hernan,Cuccovia, Iolanda M.,Bunton, Clifford A.,Moffatt, John R.
, p. 3584 - 3586 (1983)
Reaction of N-methyl-4-cyanopyridinium fluoroborate (1) with OH- in aqueous micelles of cetyltrimethylammonium hydroxide (CTAOH) occurs wholly in the aqueous pseudophase.Comparison of the rate constants in CTAOH and NaOH allows estimation of the concentrations of free and micellar bound OH-.The values of α, the fractional ionization of the micelles, decrease with increasing concentration of OH-, in agreement with evidence from reactions of substrates bound to micelles of CTAOH.
Micellar Reaction of Hydrophilic Ions: A Coulombic Model
Bunton, Clifford A.,Moffatt, John R.
, p. 4166 - 4169 (2007/10/02)
Distribution of hydrophilic ions about a spherical micelle has been estimated by using the Poisson-Boltzmann equation for finite salt and surfactant concentrations.It is consistent with rate-surfactant profiles for reactions of p-nitrophenyl diphenyl phos