4741-87-1

Basic information

• Product Name: 1,1-dimethylethylcyclopropane
• Synonyms: 1,1-dimethylethylcyclopropane
• CAS NO: 4741-87-1
• Molecular Weight: 98.1882
• Mol File: 4741-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-dimethylethylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethylethylcyclopropane(4741-87-1)
• EPA Substance Registry System: 1,1-dimethylethylcyclopropane(4741-87-1)

Safety Data

• Hazardous Substances Data: 4741-87-1(Hazardous Substances Data)

Upstream product

• 75687-68-2 3-tert-butyltitanacyclobutane 

Relevant articles and documents

Synthesis, structure, and reactions of heterobinuclear μ-methylene complexes

Sources of the reactive fragment Cp2Ti==CH2 react with a variety of late-transition-metal complexes containing μ-halides [Cl-MLn]2 to yield early-late binuclear complexes containing μ-CH2, and μ-Cl ligands. Complexes containing Rh, Ir, Pt, Pd, and Au have been prepared and characterized. The X-ray structure of the complex Cp2Ti-CH2-RhCl(COD) (COD = 1,5-cyclooctadiene) prepared from Cp2Ti-CH2C-(CH3)2-CH2 and [Cl-Rh(COD)]2 has been determined. Crystallographic data: space group Pbcm; Z = 4; a = 8.268 (2) A?, b = 16.409 (4) A?, c = 12.604 (3) A?; V = 1710 (1) A?3. The structure was refined to a final R of 0.069 and R3σ of 0.048 for the 1061 reflections that had Fo > 3σ(Fo).