475160-70-4

Basic information

• Product Name: Benzenemethanol, 4-[bis(1-methylethyl)silyl]-
• CAS NO: 475160-70-4
• Molecular Formula: C13H22OSi
• Molecular Weight: 222.403
• Mol File: 475160-70-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-[bis(1-methylethyl)silyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-[bis(1-methylethyl)silyl]-(475160-70-4)
• EPA Substance Registry System: Benzenemethanol, 4-[bis(1-methylethyl)silyl]-(475160-70-4)

Safety Data

• Hazardous Substances Data: 475160-70-4(Hazardous Substances Data)

Upstream product

• 344887-78-1 4-diisopropylsilanylbenzoic acid methyl ester 
• 2227-29-4 chlorodiisopropylsilane 
• 873-75-6 4-bromobenzenemethanol 

Downstream Products

• 301153-56-0 4-Diisopropylsilanyl-benzoic acid 
• 863331-89-9 4-(acetoxymethyl)phenyl-diisopropylsilane 
• 1133959-33-7 4-(azidomethyl)phenyldiisopropylsilane 
• 1362020-07-2 C₆₆H₉₃N₃Si₃ 
• 1362020-00-5 C₅₇H₇₃N₃Si₂ 
• 1362020-08-3 C₆₁H₇₂Br₂N₂Si₂ 
• 1362020-01-6 C₇₃H₁₀₂N₂Si₄ 
• 1362019-94-0 4-[(diisopropyl)silyl]benzaldehyde 
• 1362019-95-1 4-bromo-4'-(diisopropylsilyl)-E-stilbene 
• 1362020-02-7 4-bromo-4'-[diisopropyl(4-N,N-dimethylamino-E-styryl)silyl]-E-stilbene 
• 1362019-96-2 4-diisopropylsilyl-4'-[diisopropyl(4-N,N-dimethylamino-E-styryl)silyl]-Estilbene 

Relevant articles and documents

Crown Ether Nucleophilic Catalysts (CENCs): Agents for Enhanced Silicon Radiofluorination

New bifunctional phase transfer agents were synthesized and investigated for their abilities to promote rapid fluorination at silicon. These agents, dubbed crown ether nucleophilic catalysts (CENCs), are 18-crown-6 derivatives containing a side-arm and a potentially nucleophilic hydroxyl group. These CENCs proved efficacious in the fluorination of hindered silicon substrates, with fluorination yields dependent on the length of linker connecting the metal chelating unit to the hydroxyl group. The efficacy of these CENCs was also demonstrated for rapid radiofluorination under mild conditions for eventual application in molecular imaging with positron emission tomography (PET). The hydrolysis-resistant aryl silicon fragment is promising as a convenient synthon for labeling potential PET radiotracers.

Introduction of 3-terminal nucleosides having a silyl-type linker into polymer supports without base protection

New 3 -terminal deoxyribonucleoside-loading reagents having a silyl-type linker were developed. They were effectively introduced into polymer supports under the conditions of Huisgen [3 + 2] cycloaddition without base protection. Moreover, four unmodified

Silicon derivatives for PET imaging

This invention relates to silicon-derivated compounds suitable for labelling or already labelled with 18F, methods of preparing such a compound, compositions comprising such compounds, kits comprising such compounds or compositions and uses of